重轨钢中超低含量气体元素的快速测定.pdfVIP

重轨钢中超低含量气体元素的快速测定 ·1 · 重轨钢中超低含量气体元素的快速测定 郑连杰 张 敏 秦晓峰 （河北钢铁集团邯钢公司技术中心，河北邯郸 056015 ） 摘 要 本方法利用 LECO TCH600 型氧氮氢分析仪测定重轨钢中超低含量气体元素。用线切割机从经轧制的钢 材上取样，用碳化硅磨头和毡头对试样表面进行打磨与抛光，试样经剪切和超声波洗涤后进行分析。为保证基线 稳定，设置了充分的脱气条件和分析延迟。通过实验，发现在较高的分析功率下，空白及试样中氢含量分析结果 的精密度与低功率时没有显著区别；仪器经单标样校准后，工作曲线在用含量段准确度能够满足要求。由此确定 了氧、氮、氢三元素同时测定和单标样校准的可行性，缩短了实验周期。用该方法分析标准物质，测定值与参考 值一致，试样中氧、氮、氢分析的精密度（n=6 ）分别为2.92% 、0.86%和 3.68% 。该方法快速简便，能够为重轨 钢的生产与判定工作提供及时、可靠的数据。 关键词 重轨钢，氧，氮，氢，快速测定 Rapid Analysis of Ultra Low Gaseous Elements in Heavy Rail Steel Zheng Lianjie, Zhang Min, Qin Xiaofeng (Technique Center, Handan Iron and Steel Company, Handan 056015, China) Abstract Concentration of ultra low gaseous elements in heavy rail steel were determined by LECO TCH600 hydrogen/nitrogen/oxygen determinator. The samples were obtained in rolled steel by wire cutting machine, burnished by carborundum drill head and felt drill head, cut and ultrasonic washed, and then analysed. Sufficient outgas conditions and analysis delay were configured to obtain stable baselines. The tests proved that the precision of hydrogen under high analysis power made little difference to that obtained under low analysis power. And the accuracy of the required sections of the working curves were satisfying. So the feasibility of simultaneous determination of oxygen, nitrogen and hydrogen and single standard calibration were proved, which reduced the time cost of the experiment. The analysis results of standard sample were accordant with the referenced value. The RSD (n=6%) oxygen, nitrogen and hydrogen in production samples were 2.92%, 0.86% and 3.68%. This method is fast and simple, and it c