UV光引发丙烯酰胺反相微乳液聚合研究-河北科技大学学报.PDF

28 4 Vol. 28, No .4 2007 12 Journal of Hebei University of Science and T ec nology Dec. 2007 : 1008-1542( 2007) 04-0292- 06 UV 安 静, 王德松, 李雪艳, 罗青枝 ( 河北科技大学理学院, 河北石家庄 050018) : 采用光引发聚合技术, 选取合适的光引发剂进行丙烯酰胺( AM) 反 微乳液聚合用U V 6 光引发AM/ 水/ 白油/ ( Span80+ OP- 10) 体系聚合, 所得聚合物粘均 对分子质量可达 10 考察 了光引发剂类型及质量分数单体质量分数乳化剂质量分数和聚合时间等对聚合反应的影响, 得 到了光引发合成聚合物的较优工艺条件通过红外光谱法鉴定出所得聚合物为聚丙烯酰胺 ( PAM) : 光引发; 丙烯酰胺; 反 微乳液聚合; 对分子质量 : O632. 5 : A Inverse microemulsion polymerization of acrylamide initiated by UV radiation AN Jing, WANG De-song, LI Xue-yan, LU O Qing- z i ( College of Sciences, H ebei University of Science and Tec nology , S ijiaz uang H ebei 050018, C ina) Abstract: P otoinitiat ion tec nic w as developed to polymerize acrylamide in an inverse microemulsion system by c oosing t e rig t lig t init iator . Using Span80 + OP- 10 as a blend emulsifier, t e inverse microemulsion polymerization of acrylamide in 6 w ite oil could be complet ed by UV lig t radiat ion, and t e molecular w eig t of t e produced polymer was as ig as 10 . T e effects of t e type and concent ration of p ot o-initiator, monomer concentration, emulsifier concentration and polymerization time w ere investigated, and a relatively good condition for polymerization of AM by U V radiation was acquired. T e polymer was ident ified as PAM by IR spect rum. Key words: p otoinitiation; acrylamide; inverse microemulsion polymerization; molecular weig