二次插层蒙脱土的制备及其对环氧涂层耐蚀性的影响-OALib.PDF

第28 卷 第9 期 材 料 研 究 学 报 Vol. 28 No. 9 2 0 1 4 年 9 月 CHINESE JOURNAL OF MATERIALS RESEARCH September 2 0 1 4 二次插层蒙脱土的制备及其对 环氧涂层耐蚀性的影响* 1 2 1 2 1 2 2 刘明明 尹桂来 刘福春 唐 囡 韩恩厚 万军彪 邓静伟 1. 中国科学院金属研究所 中国科学院核用结构材料与安全性评价重点实验室 沈阳 110016 2. 国网江西省电力科学研究院 南昌 330096 摘要使用两步插层方法制备了插层蒙脱土, 用红外光谱(IR)和X 射线衍射(XRD) 图谱对插层效果进行了表征。结果表明, 十八烷基胺以及8-羟基喹啉已进入蒙脱土层间, 蒙脱土层间距分别由1.17 nm 增加到1.57 nm 和1.82 nm 。EIS 结果显示插层 蒙脱土显著提高了环氧涂层的耐蚀性。 关键词 有机高分子材料, 蒙脱土, 插层剂, 防腐蚀涂料, 输变电设备 分类号 TG 174 文章编号 1005-3093(2014)09-0668-07 Preparation of Montmorillonite by Two-step Intercalation and Its Effect on the Corrosion Resistance of Epoxy Coatings LIU Mingming1 YIN Guilai2 LIU Fuchun1** TANG Nan2 HAN Enhou1 WAN Junbiao2 DENG Jingwei2 1. Key Laboratory of Nuclear Materials and Safety Assessment, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 2. State Grid Jiangxi Electric Power Research Institute, Nanchang 330096 *Supported by National Science and Technology Support Program No.2012BAB 15B00 and State Grid Practical Project No.521820130014. Manuscript received April 1st, 2014; in revised form May 15, 2014. **To whom correspondence should be addressed, Tel: (024 E-mail: fcliu@imr.ac.cn ABSTRACT Two- step intercalation montmorillonites were prepared with montmorillonites (MMTs) as