化学反应工程第三部份讲义.PDF

化學反應工程第三部份講義 Textbook: Fogler, Elements of Chemical Reaction Engineering Chapter 10 Catalysis and Catalytic Reactors Catalysts Catalytic reactions Rate expression Mechanism Reactor design Chemical Vapor Deposition (CVD) Deactivation Reactors-packed bed, fluidized bed, moving bed Chapter 11 External Diffusion Effects on Heterogeneous Reactions Diffusion Fundamentals Binary Diffusion External Resistance to Mass Transfer Chapter 12 Diffusion and Reaction Diffusion and reaction in spherical catalyst pellets Internal effectiveness factor Overall effectiveness factor Determination of limiting situations from reaction data • Grading – Quiz (every Tuesday) 25% – Final Exam 75% – Participation 5% – Homework 0% Chapter 10 Catalysis and Catalytic Reactors Objective: To develop an understanding of catalysts: define a catalyst and describe its properties reaction mechanism: describe the steps in a catalytic reaction and apply the concept of a rate-limiting step to derive a rate law catalytic reactor design Contents: Catalyst definitions and properties Steps in catalytic reactions Rate expression and parameters Catalyst deactivation Catalytic reactors Conversion or catalyst weight for reactors Chemical vapor deposition ( CVD ) References: 1.翁鴻山老師講義 2. G. C. Bond: Heterogeneous Catalysis, Oxford, 1987. 胡興中編譯( :觸媒原理與應用 , 高立 ) 3. 科學發展（月刊），第 370 期(92 年10月) （觸媒專輯） 10−1 1. Catalysts 。A catalyst is a substance that affects the rate of a reaction b