受限薄膜中不对称两嵌段共聚高分子的微相形态-上海有机化学研究所.PDF

2004 年第 62 卷 化 学 学 报 Vol. 62 , 2004 第 17 期 , 1601～1606 ACTA CHIMICA SINICA No. 17 , 1601 ～1606 受限薄膜中不对称两嵌段共聚高分子的微相形态 杨颖梓 　　邱　枫 　　张红东　　杨玉良 (复旦大学高分子科学系 　教育部聚合物分子工程重点实验室 　上海 200433) ( ) 摘要 　用强分凝理论方法研究了组分不对称 f ≈025 的两嵌段共聚高分子在受限薄膜中的微相形态 ———层状相、平行柱 状相和垂直柱状相. 发现对中性基底 ,无论薄膜厚度为多少 ,垂直柱状相总是最稳定的相 ;而对亲少数相的基底 ,嵌段高分 ( 子的平均组成以及基底和两嵌段之间的相互作用能对薄膜体系的相行为有决定性影响. 随着薄膜厚度的增加 ,层状相 包 ) 括奇数和偶数层数 、平行柱状相和垂直柱状相都有可能交替出现. 关键词 　两嵌段高分子 ,薄膜 ,微相形态 ,柱状相 ,层状相 ,强分凝理论 Microphases of Asymmetric Diblock Copolymers in Confined Thin Films YANG, YingZi 　　QIU , Feng 　　ZHANG, HongDong 　　YANG, YuLiang ( Department of Macromolecular Science , Key Laboratory of Molecular Engineering of Polymers , Ministry of Education , Fudan University , Shanghai 200433) Abstract 　Microphase formation of an asymmetric diblock copolymer (with f ≈025) confined in a thin film was investigated by using strong segregation theory. The stability of microphases , such as surfaceparallel lamella , surface parallel and surfaceperpendicular cylinders , was determined. It was found that for neutral substrates the surface perpendicular cylinders are always stable as the film thickness is varied. However , for substrates that prefer the minor compone