筒仓预应力筋长期损失分析.pdfVIP

第29 卷 第6 期 无 机 材 料 学 报 Vol. 29 No. 6 2014 年6 月 Journal of Inorganic Materials Jun., 2014 Article ID: 1000-324X(2014)06-0667-06 DOI: 10.3724/SP.J.1077.2014.14039 Sol-Gel Preparation of PHFBMA/PFG/Silica Coatings with Durable Shortwave-band Antireflective Performance ZHANG Qing-Hua, HUI Hao-Hao, YANG Wei, WEI Yao-Wei, WANG Jian, XU Qiao (Chengdu Fine Optical Engineering Research Centre, Chengdu 610041, China) Abstract: A new silica shortwave-band antireflective (AR) coating with durable optical performance on fused silica substrate was prepared by a base-catalyzed Sol-Gel process using tetraethyl orthosilicate (TEOS) as a precursor. 1H, 1H, 12H, 12H-perfluoro-dodecane-1, 12-diol (simplified as PFG) was used to control the structure and size of the sil- ica particles in the sols, and hence decreased the refractive indices of the coatings. After Poly (2, 2, 3, 4, 4, 4-hexafluorobutyl) methacrylate (PHFBMA) being introduced into the silica sols, the AR coatings could retain a transmission about 99.9% at about 300 nm. At the same time, the transmission stability of the coatings was improved significantly, which were tested in a moisture environment and an organic-containing vacuum chamber, respectively. Key words: antireflective coating; Sol-Gel; shortwave-band; hydrophobicity; organic contamination As a potential pollution-free high power tool, consider- transmission of 99.9% was obtained at about 300 nm, and able interest has been gi