金属氧化物与现代微电子学——过渡金属前体化合物及转化为材料的化学过程（英文）.docVIP

金属氧化物与现代微电子学——过渡金属前体化合物及转化为材料的化学过程（英文） Tabitha M.Cook Adam C.Lamb 薛子陵 田纳西大学化学系 X 关注成功！ 加关注后您将方便地在 我的关注中得到本文献的被引频次变化的通知！ 新浪微博 腾讯微博 人人网 开心网 豆瓣网 网易微博 摘????要： 金属氧化物薄膜如HfO2 (被称为高k电介质) 是现代微电子器件的关键组件, 广泛用于计算机 (平板电脑, 笔记本电脑和台式机) 、智能电话、智能电视、汽车和医疗设备中。具有大介电常数 (k) 的金属氧化物已经取代了介电常数小的SiO2 (k=3.9) , 从而使得微电子元件进一步小型化。过渡金属化合物在化学气相沉积 (CVD) 和原子层沉积 (ALD) 中被广泛用作前体, 通过与O2、H2O或O3的反应生成金属氧化物薄膜。微电子金属氧化物膜是纳米材料最广泛应用的一个领域。本文概观该领域的最新进展, 包括我们对d0过渡金属配合物与O2反应的研究。 关键词： 金属氧化物; 栅极电介质材料; 薄膜; 微电子学; 化学气相沉积; 原子层沉积; 作者简介：薛子陵 E-mail:xue@ 收稿日期：2017-07-26 基金：美国国家科学基金会 (No.CHE-1633870) 资助项目 Metal Oxides and Modern Microelectronics:Roles of Transition Metal Compounds and their Conversion to the Materials Tabitha M.Cook Adam C.Lamb XUE Zi-Ling Department of Chemistry, The University of Tennessee; Abstract： Thin films of metal oxides such as HfO2[known as high k dielectrics (or metal gate) ] are a key component of modern microelectronic devices in computers (tablet, laptop and desktop) , smartphones, smart TVs, automobiles and medical devices. The metal oxides, with large dielectric constants ( k) , have replaced SiO2 that has a small k of 3.9, thus making it possible to further miniaturize microelectronic components. Transition metal complexes have been widely used as precursors to produce thin films through their reactions with O2, H2O or O3 in chemical vapor deposition (CVD) and atomic layer deposition (ALD) processes. The microelectronic metal oxide films are one of the most widely used nano materials. Recent progresses, including our studies of the reactions of d0 transition metal complexes with O2, are overviewed. Keyword： metal oxides; gate dielectrics; thin films; microelectronics; CVD; ALD; Received： 2017-07-26 0 Introduction Microelectronic devices are a major part of society today.There has been a continuous drive to make computers, tablets, smartphones and other such devices smaller, faster and more efficient.Over the past few decades, there has been steady progress in this area followi