陶粒论文：陶粒 表面改性 吸附 水污染 腐植酸.docVIP

【关键词】陶粒 表面改性 吸附 水污染 腐植酸 【英文关键词】Ceramic Mediums Surface Modification Adsorption WaterContamination Humic Acid 陶粒论文：陶粒表面涂覆改性及其吸附性能研究 【中文摘要】水是生物体最重要的组成部分,是生命之源。然而,随着人类社会的进步及工业的不断发展,水污染不断加剧,由此导致的水资源短缺及水质恶化对生态环境、人类健康以及社会的发展都造成了巨大的威胁。面对新的污染形势,传统的水处理工艺已经很难满足净化水质的要求。如何改进工艺,改善现有的水处理设备的出水水质成为目前的一个重要的研究方向。本实验以甘肃某公司生产的粘土-粉煤灰烧结陶粒为载体,以氯化铁为改性剂对其进行了表面改性,制得氯化铁改性陶粒。以其对葡萄糖模拟人工废水CODcr的吸附去除率作为评价改性效果的标准,优化了改性条件,包括pH值、改性剂浓度、焙烧温度、焙烧时间及涂覆次数。实验确定的最优改性条件为pH=3,改性剂浓度为2mol/L,焙烧温度为650℃,焙烧时间为3h,涂覆次数为2次。与未做改性的原陶粒进行对比,改性后陶粒的比表面积是原陶粒的2.75倍。经过改性,陶粒的孔体积明显增大。X衍射的结果表明改性陶瓷滤料表面氧化膜主要为α-Fe2O3另外有少量的α-FeOOH。对比不同条件下制得的改性陶粒的表面形态发现,反应条件对改性后陶粒的表面氧化物晶体形态有很大的影响。而氧化物晶体的形态对改性陶粒的比表面积及其吸附性能都有很大的影响。研究发现,当pH=3、改性剂浓度为2mol/L、焙烧温度为650℃-750℃、焙烧时间为3h时在陶粒的表面形成细小球状的氧化物晶体,排列成多孔的氧化铁涂层,这有利于增大陶粒的比表面积,提高陶粒的吸附性能。研究了所制得的氯化铁改性陶粒对腐植酸的吸附性能。结果表明,氯化铁改性陶粒对腐植酸的吸附性能有很大的提高。对其吸附条件进行了优化,包括pH值、振荡时间、吸附剂投加量、温度及盐浓度。结果表明,在pH=11.0,温度为35℃,时间为6h,吸附剂投加量为7g, NaCl浓度为0.12mol/L时改性陶粒对腐植酸的去除率最高为62.01%。对吸附实验数据进行了模型拟合,结果显示,氯化铁改性陶粒对腐植酸的吸附符合准二级动力学方程和Freundlich等温吸附模型 【英文摘要】Water is the most important part of the living organisms and an important resource of all life including humans. However, with the progress of human society and the continuous development of industry, water pollution is more and more serious, which has led to the shortage of water resources and the deterioration of water quality. This caused great threat to the health of human beings and the development of the society. In the face of the new situation, the traditional water treatment process has been difficult to meet requirements of purifying water quality. How to improve the process and the existing water treatment equipment for the effluent water is one of the important research direction.In the present study, a kind of clay-fly ash sintered ceramic mediums produced by a company in Gansu province was used as the carrier and ferric chloride as modifying agent for the surface modification. The COD removal rate of the artificial wastewater was used as evaluation standard of