离心萃取论文：环隙式离心萃取回收己内酰胺废液的研究与应用.docVIP

环隙式离心萃取回收己内酰胺废液的研究与应用 【中文摘要】己内酰胺(CPL)是聚酰胺6纤维和塑料的重要生产原料,在其精制工序会产生大量废液,废液中己内酰胺平均含量约2wt.%,造成产品大量流失。针对己内酰胺废液回收问题,开发了环隙式离心萃取工艺,用Φ50mm环隙式离心萃取机进行己内酰胺回收冷模优化实验,研究了不同操作条件和几何尺寸对传质效率和分离性能的影响,在保证相夹带低于0.5%以下时,传质效率最高可达99.8%,最大分离容量为109L/h：同时,从数值模拟出发,以相同尺寸的环隙式离心萃取机为研究对象,采用Fluent软件计算了不同条件下的环隙单相流场,研究了内在的传质机理,模拟所得的流场结构特征能够很好地解释实验结果。依托20万吨/年己内酰胺工程项目,采用Φ350mm环隙式离心萃取机建成工业装置,在废液流量为1m3/h,苯量为3.5 m3/h,转速为900r/min时,相夹带低于0.5%,回收效率可达到75.3%,废液平均己内酰胺含量可降至0.7%以下,具有十分突出的经济效益。 【英文摘要】Caprolactam (CPL) is raw material to polymerize Nylon6 and engineering plastics. During the refine procedure of CPL production, a large amout of CPL-containing wastewater is produced, and the average mass concentration of CPL is about 2%. The discharge of CPL-containing wastewater causes a big loss of products.To deal with the problem above, a new extraction technology which is called as centrifugal extraction is proposed to reclaim CPL from the wastewater. In this paper, a cold mold experiment was conduted with (?)50mm annular centrifugal extractor. Effects of different operation conditions and geometry dimentions on the mass transfer efficiency and separation performance were studied. Results show that the highest mass transfer efficiency is 99.8% and the maximum separation capacity can reach 109L/min when the phase entrainment is under 0.5%. Furthermore, CFD simulation was used to study the mechanism of mass transfer in the annulus. The same operation conditions and geometry dimentions as the experimental device were simulated by the software Fluent 6.3.26. The ruslts are consistent with the experiment.Depend on 200,000 tons/y production project of CPL,(?)350mm annular centrifugal extractor was used to build the industrial equipment. Under nomal conditions, the recovery efficiency can reach to 75.3% and the concentration of CPL can be reduced to below 0.7% when the phase entrainment is under 0.5%, which is siginifigent to ecomomic and environment protection. 【关键词】离心萃取 己内酰胺 计算流体力学(CFD) 环隙流场 【英文关键词】Centrifugal extraction