锂离子电池用负极材料金属氢化物的进展.pdfVIP

Rare Metal Materials and Engineering Volume 41, Suppl. 2, September 2012 Cite this article as: Rare Metal Materials and Engineering, 2012, 41(S2): 688-692. Current Researches on Metal Hydride as Anode Material in Lithium Ion Batteries Huang Lihong 1, 2, Zhu Ding 1, Chen Yungui 1 1 2 Sichuan University, Chengdu 610065, China; Inner Mongolia University of Technology, Huhhot 010051, China Abstract: Classical electrodes for lithium-ion batteries work through via an insertion/de-insertion process. Recently, metal hydride electrodes have attracted attention owing to their competitively theoretical capacities in a potential window of 0.1~0.5 V vs. Li+/Li and the lowest polarization among conversion electrodes which have shown the capability of greater capacity. This review here describes some recent developments in the discovery of metal hydride anodes for lithium-ion batteries and presents their electrochemical reactivity with Li. The characteristics, advantages and disadvantages of metal hydride anodes for lithium-ion batteries are highlighted. Key words: metal hydride; anode; conversion reaction; lithium-ion battery The performance of lithium ion batteries (LIBs) depends As we all know, metal hydrides (MH) have been widely closely on the properties of their anode and cathode materi- used in nickel-metal hydride batteries and solid state hy- als. In resent years, novel anode materials with higher ca- drogen storage. It can be divided into two types, namely, pacity have attracted great interests to replace graphite an- alkali/alkaline earth metal hydride (salt type) and transi- ode used in todays commercial LIBs mostly[1]. One of the