【精选】[H(OEt2)2]+ and [Ph3C]+ Salts of the Borate Anions [B(CF3)4]-, [(CF3)3BCN]-, and [B(CN)4]-[H(OEt2)2]+ and [Ph3C]+ Salts of the Borate Anions [B(CF3)4]-, [(CF3)3BCN]-, and [B(CN)4]-.pdf

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【精选】[H(OEt2)2]+ and [Ph3C]+ Salts of the Borate Anions [B(CF3)4]-, [(CF3)3BCN]-, and [B(CN)4]-[H(OEt2)2]+ and [Ph3C]+ Salts of the Borate Anions [B(CF3)4]-, [(CF3)3BCN]-, and [B(CN)4]-.pdf

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【精选】[H(OEt2)2]and[Ph3C]SaltsoftheBorateAnions[B(CF3)4]-,[(CF3)3BCN]-,and[B(CN)4]-[H(OEt2)2]and[Ph3C]SaltsoftheBorateAnions[B(CF3)4]-,[(CF3)3BCN]-,and[B(CN)4]-

Organometallics 2005, 24, 5103 [H(OEt ) ] and [Ph C] Salts of the Borate Anions 2 2 3 [B(CF ) ] , [(CF ) BCN] , and [B(CN) ] 3 4 3 3 4 Maik Finze,*,†,§ Eduard Bernhardt,† Michael Berkei,† Helge Willner,*,† Joyce Hung,‡ and Robert M. Waymouth*,‡ FB C-Anorganische Chemie, Bergische Universita¨ t Wuppertal, Gaussstrasse 20, D-42097 Wuppertal, Germany, and Department of Chemistry, Stanford University, Stanford, California 94305 Received June 8, 2005 The reaction of gaseous HCl with K[B(CF ) ] in diethyl ether gave the oxonium acid 3 4 [H(OEt ) ][B(CF ) ] as a stable salt at room temperature. Syntheses of [Ph C][B(CF ) ] and 2 2 3 4 3 3 4 [Ph C][(CF ) BCN] were accomplished from the corresponding potassium salts and Ph CCl. 3 3 3 3 The metathesis reaction of Ag[B(CN) ] with trityl bromide resulted in formation of [Ph C]-