沸石zsm-5增强聚乳酸的热稳定性研究-国家级大学生创新创业训练.pdfVIP

沸石ZSM-5增强聚乳酸的热稳定性研究 天津商业大学 郝宇华，黄震，王静文，杨心语，范兴月，李亚丽1 （1.天津商业大学机械工程学院包装工程系，天津市300134） （PolymerTesting，2015年11月） 指导教师：黄震 教授 ： TG DTA PLLA/ZSM-5 中文摘要 利用热重分析 （ ）和差热分析 （ ）测定两种 沸石混合材料以研究沸石对聚合物热降解的影 响。热分析在流率为30mL/min 的氮气中进行，升温速率范围为5-30K/min，然后从TG 和DTA 实验曲线分析样品的热降解 性能。结果表明，热分解主要发生在580-690K 的温度范围内，而且加入ZSM-5 沸石显著提高了PLLA 的热稳定性。通过 Flynn-Wall-Ozawa Coats-Redfern Madhusudanan-Krishnan-Ninan 用 ， 和 等三种不同的温度积分方法对实验数据进行动力学分 析。在采用一级反应假定的条件下计算得到活化能和指前因子值，均高于纯PLLA 的对应值。表明加入ZSM-5沸石后需要 更高的活化能才能发生热降解反应，可能是PLLA 的热稳定性得到增强之故。利用所得动力学参数和上述分析方法模拟了材 TG 料的 曲线，取得了良好的拟合效果。 英文摘要:Thermogravimetric (TG) analysis and differential thermal analysis (DTA) measurements were conducted on ZSM-5 zeolite/poly (L-lactide) (PLLA) composites with two different zeolite loadings. The experimental data were collected under nitrogen atmosphere with heating rates of 5-30 K/min and the thermal featureswere examined from resultant TG and DTA curves.The results show that one-stage thermal decomposition mainly occurs in the temperature range 580-690 K, and the incorporation of ZSM-5 zeolite has substantially boosted the thermal stability of PLLA. Kinetic analysis of the mass loss versus temperature data was performed with different temperature-integral methods, the Flynn-Wall- Ozawa, Coats-Redfern and Madhusudanan-Krishnan-Ninan methods. With the first order reaction assumption, the activation energy and pre-exponential factor values can be readily obtained over the entire conversion range, and they are both much higher than those of pure PLLA. The ZSM-5 zeolite-filled composites required higher Ea values for thermal decomposition than pure PLLA, possibly resulting from enhanced thermal stability. With kinetic parameters thus obtained, the thermal conversion curves ha