尼龙12弹性体延伸薄膜之探讨-华冈纺织期刊JournaloftheHwa.PDF

JHGT 2017.10, Vol.24, No.8(534-538) Journal of the Hwa Gang Textile 華岡紡織期刊第二 十四卷第八期 ISSN 1025-9678 .tw/pdf/jhgt-24.8(534-538)(2017-10).pdf 尼龍 12 彈性體延伸薄膜之探討 Oriented Film Properties of Nylon 12 Elastomer 劉弘仁 Hung-Jen Liu 工業技術研究院 Industrial Technology Research Institute chieryliu@.tw 摘要 本研究利用雙螺桿押出機押出尼龍 12 彈性體薄膜，並進行不同倍率雙軸延伸，研究薄膜熱性 質與結晶取向關係 。首先使用示差掃描量熱儀進行熱性質分析 ，並探討尼龍 12 彈性體結晶動 力學 。再來分析雙軸延伸尼龍薄膜之性質，包括光學性質、氧氣穿透率及水蒸氣穿透率 ，以 及探討薄膜之延伸與結晶度之間的關係。 關鍵字：尼龍 12,彈性體 , 雙軸延伸, 結晶 Abstract In this study, Nylon 12 elastomer film was casted by twin screw extruder and followed by bi-axially stretching with various ratios. In the first part, the thermal properties and crystallization kinetics were analyzed by measuring the heat flow in the adiabatic process by using differential scanning calorimetry (DSC). Furthermore, the properties of BOPA film were analyzed including optical properties, oxygen transmission rate (OTR), water vapor transmission rate (WVTR) and the relationship among the stretching and the crystallinity. Keywords ：Nylon 12, Elastomer, Bi-Axially Orientation, Crystallization 534 Journal of the Hwa Gang Textile, 2017.10, Vol.24, No.8 前言 整度、尺寸穩定性、耐磨損