聚二甲基硅烷高温高压合成聚碳硅烷工艺研究-复合材料学报.PDFVIP

39 Synthesis of Polycarbosilane from Polydimethylsilane at High Temperature and High Pressure , , , , ( , 410073) HENG Xiang-zhen, SONG Yong-cai, XIE Zheng-fang, XIAO Jia-yu, Wang Ying-de (State Key Lab of Novel eramic Fibers omposites, Institute of Aerospace and Materials Engineering, National University of Defense T echnology, hangsha 410073, hina) : ( PDM S) , (P S) , Si- H , , , , , 460 46 , 450 67 , 200220 , PDMS h h P S 5%10 % ( ) , Si- H 0.9, , Si : ; ; : T Q343: A: 1001-4381 (2004) 08-0039-05 Abstract : The polycarbosilane (P S) , the precursor of Si fiber, was synthesized at high tempera- ture and high pressure by thermal decomposition of polydimethylsilane (PDMS) . The influence of synthesis conditions on final pressure at room temperature, Si- H bond content, P S yield, soften- ing point, the molecular weight and distributions, and spinnability were investigated. The results show that the molecular weight and softening point of P S increase while the reaction temperature increase T he spinnability of P S decreases gradually with temperature. Suitable reaction time for the synthesis of P S from PDMS in autoclave should be 46h at 460 , or 67h at 450 . The as- synthesized P S, in which the high molecular weight content was about 5% 10% ( mass fraction) 200 220 , - 0.9, , with softening point about to Si H bond content more than and good spinnability was the suitable precursor for the preparat