过量PbO对TGG法制备0675PMN-0325PT织构-中国有色金属学报.PDFVIP

18 7 2008 7 Vol.18 No.7 The Chinese Journal of Nonferrous Metals Jul. 2008 1004-0609(2008)07-1292-07 PbO TGG 0.675PMN-0.325PT ( 410083) 0.675PMN-0.325PT001SrTiO 3 0.675PMN-0.325PT PbOPbO− PMNT 3%PbO1 000 2 h40% PMN-PT PbO 0.675PMN-0.325PT TGG TM 28 A Effect of excess PbO on preparation textured 0.675PMN-0.325PT ceramics by TGG method WEN Jia, ZHOU Ke-chao, LI Zhi-you, ZHANG Xiao-yong (State Key laboratory of Powder Metallurgy, Central South University, Changsha 410083, China) Abstract: Textured 0.675PMN-0.325PT polycrystalline ceramics with certain orientation degree were prepared using mixed oxide powders 0.675PMN-0.325PT as matrix and 001 tabular SrTiO3 as templates at relative low temperatures by templated grain growth technique. The effects of self-growth of matrix grains during sintering process, epitaxial growth of templates and excess PbO on texture formation were also studied. The results show that the increase of excess PbO can accelerate the dissolution-precipitation process of the matrix, and then improve the matrix grains growth. Meanwhile, the increase of liquid content also can promote both epitaxial growth of template and formation of textures. The sintering temperatures when reactive material used as matrix are much lower than those when PMNT used as matrix. Holding at 1 000 for 2 h, the textured PMN-PT ceramic with orientation degree of 40% are obtained after adding 3% excess PbO. Key word: PbO; textured 0.675PMN-0.325PT; TGG method; polycrysta