包覆纳米镍粒子的碳纳米管磁性研究_英文_.docx

MA GNETIC PROPERTIES OF CARBO N NANOTUBESENCAPSUL ATING NANOSIZED NIC KEL PARTICL ESL EI Zhong2xing1 ,L I Xuan2ke1 ,WAN G Hou2zhi1 ,HON G Xue2qing2 ,CHEN J ia2wei2(1 . The Center of Nano2Materials and Technology , Wuhan University of Science and Technology , Wuhan 430081 , China ;2 . Wugang Ref ractory Co. Ltd . , WIS CO , Wuhan 430082 , China)ABSTRACT: Multi2walled carbon nanotubes were synthesized by the catalytic chemical vap or decomp osition method , and a binary aerogel with a 1. 20∶1 nickel2silica weight ratio was used as catalyst , which was p repared by the sol2gel supercritical fluiddrying method . The synthesis of carbon nanotubes was conducted in a quartz tube f urnace . The catalysts in the quartz boat were heat2treated to the required temperature under nitrogen atmosp here and reduced by flowing hydrogen f or 30 min . Then the gas mixture of hydrogen and methane was introduced into the f urnace and p yrolyzed f or 30 min～60 min . Finally , the p roduct ob2tained was cooled to room temperature under a nitrogen atmosp here . The samples were characterized by XRD , S EM , TEM , HRTEM , Raman spectra and susceptibility tests . The results showed that the p yrolytic p roduct was comp osed of multi2walled carbon nanotubes and nanosized nickel particles , which were encapsulated at the tip of the carbon nanotubes . Magnetic analysis showed that the carbon nanotubes encapsulating nickel had a specific saturation magnetization of 0. 66 A·m2 ·kg - 1 and a coerciv2 ity of 20 157 A·m - 1 .KEY WO RDS : Carbon nanotubes ; Magnetic p roperties ; MicrostructureCLC number : TB 383 TQ 127. 1 + 1Document code : Amethane and hydrogen was introduced into the f urnace to decomp ose . After decomp osition reaction , the obtained p roduct is cooled to room temperature under nitrogen at 2 mosp here . The p ristine samples and the p urified samples were used in test .In this paper , the imp ortant parameters s uch as the static suscept