再生水中腐殖酸对铸铁管的腐蚀机制研究-腐蚀科学与防护技术.PDFVIP

再生水中腐殖酸对铸铁管的腐蚀机制研究 1 1 2 3 1 1 冯萃敏 ,安鑫悦 ，张欣蕊 ，尹晓星 ，郭子玉 ，李欣悦 1.北京建筑大学城市雨水系统与水环境教育部重点实验室，北京 100044； 2.北京市市政工程设计研究总院有限公司，北京 100082； 3.江西应用技术职业学院，江西 341000 摘要：以中国北方某再生水厂的出水为研究对象，重点围绕特征有机物腐殖酸对铸铁腐蚀的 影响开展试验研究，应用 X 射线衍射、扫描电镜等手段，探讨了再生水中腐殖酸对铸铁腐蚀 形貌、腐蚀生长过程及腐蚀形成机制的影响。试验结果表明，在反应初期，再生水中的腐殖 酸与铸铁表面反应形成稳定的吸附膜抑制铸铁表面的腐蚀，随着反应时间的推移，逐渐生长 的污垢将吸附膜破坏形成腐蚀，再生水中腐殖酸浓度为 6mg/L 时腐蚀速率最小，因此，再生 水中腐殖酸浓度过高和过低都不利于腐蚀控制。 关键词：再生水，铸铁管，腐殖酸，腐蚀机制 中图分类号： Research on Humic Acid’s Effects to Cast-iron Pipe Corrosion in Reclaimed Water FENG Cuimin1 1 2 3 , AN Xinyue , ZHANG Xinrui ，YIN Xiaoxing , 1 1 GUO Ziyu , LI Xinyue 1.Key Laboratory of Urban Stormwater System and Water Environment, Ministry of Education,Beijing University of Civil Engineering and Architecture, Beijing 100044, China; 2. Beijing General Municipal Engineering Design Research Institute Co., Ltd, Beijing 100082, China; 3. Jiangxi College of Applied Technology, Jiangxi341000 Correspondent: FENG Cuimin, E-mail: feng-cuimin@ Supported by National Natural Science Foundation of China Manuscript received, in revised form Abstract:Aexperimental research based on reclaimed water plant effluent in northern China was conducted for corrosion morphology, formation and growth mechanism under the influence of humic acid (HA) in reclaimed water by applying X-ray diffraction (XRD), scanning electron microscopy (SEM) and other measurement. The results indicate that HA retards corrosion in the early reaction period due to forming stable adsorption film, however, as time goes by it was destroyed by growing corrosion fouling, and the minimum