刚玉质微孔耐火材料的制备及性能.docx

2013年3月March，2013JOURNALOFTHECHINESECERAMICSOCIETYDOI：10.7521/j.issn.0454–5648.2013.03.25刚玉质微孔耐火材料的制备及性能朱伯铨，魏国平，李享成，宋雅楠(武汉科技大学，耐火材料与高温陶瓷国家重点实验室培育基地，武汉430081)摘要：以板状刚玉骨料(粒度为0.088～1.000mm)及细粉(粒度分别为0.045～0.088mm和小于0.045mm)、活性α-Al2O3微粉(d50=1.75μm)和ρ-Al2O3微粉(d50=1.5μm)为主要原料，采用浇注成型工艺制备刚玉质微孔耐火材料。研究了纳米Al2O3添加量(其质量分数分别为0、0.5%、1.0%和1.5%)对刚玉质微孔耐火材料常规物理性能和高温热导率的影响。结果表明：随纳米Al2O3添加量增加，样品的体积密度、常温耐压强度和常温抗折强度均逐渐增大，显气孔率逐渐减小。纳米Al2O3的引入在一定程度上起到细化气孔的作用。随纳米Al2O3添加量增加，样品气孔的体积中位径由0.90?m降低到0.68?m；样品的弹性模量逐渐下降，且气孔的体积中位径与样品的弹性模量间有较高的线性相关性；样品在300～1000℃的热导率逐渐下降：300℃时的热导率从0.627W/(m·K)降低到0.200W/(m·K)，1000℃时的热导率从1.029W/(m·K)降低到0.778W/(m·K)。关键词：刚玉；纳米氧化铝；微孔；热导率；弹性模量中图分类号：TQ175.1文献标志码：A文章编号：0454–5648(2013)03–0422–05网络出版地址：/kcms/detail/11.2310.TQ1108.201303.422_025.html网络出版时间：2013–02–2811:08:39PreparationandPropertiesofCorundumBasedMicroporousRefractoryZHUBoquan，WEIGuoping，LIXiangcheng，SONGYanan(TheStateKeyLaboratoryCultivationBaseofRefractoriesandCeramics,WuhanUniversityofScienceandTechnology,Wuhan430081,China)Abstract:Aseriesofcorundumbasedmicroporousrefractorieswerepreparedviacastingprocesswithtabularaluminaaggregates(0.088–1.000mm)andfinepowders(0.045–0.088mmand0.045mm,respectively),reactiveα-Al2O3micro-sizedpowder(d50=1.75μm)andρ-Al2O3micro-sizedpowder(d50=1.5μm)asstartingmaterials.Theinfluenceofnano-Al2O3addition(0,0.5%,1.0%and1.5%inmass)onthephysicalpropertiesandthermalconductivityofcorundumbasedmicroporousrefractorywasinvestigated.Theresultsshowthatthebulkdensity,compressivestrengthandbendingstrengthofspecimensincrease,andtheapparentporositydecreasesgraduallywiththeincreaseofadditionofAl2O3nano-particles.ItwasfoundthattheporesizeofspecimensreducedduetotheadditionofAl2O3nano-particles.Withtheincreaseofnano-Al2O3addition,themedianporesizeofthespecimensdecreasedfrom0.90?mto0.68?m,thethermalconductivityat300–1000℃andthemodulusofelasticityofspecimensbothalsodecreased,andtheirthermalconductivitiesdereasedfrom0.627W/(m·K)to0.200W/(m·K)(at300℃)andfrom1.029W/(m·K)to0.778W/(m·K)(at1000℃),respect