砷黄铁矿生物氧化的电化学研讨.pdfVIP

砷黄铁矿生物氧化的电化学研究* 袁秋红，张广积，杨超** （中国科学院过程工程研究所，绿色过程与工程重点实验室，北京 100190） 摘要：以天然砷黄铁矿矿物晶体为工作电极，利用循环伏安和交流阻抗的方法，研究其在接种氧化亚铁硫 杆菌或添加三价铁离子的酸性培养基中发生氧化时的电化学响应。结果表明：在有菌体系，砷黄铁矿首先 在50 mv (vsSCE)附近氧化生成亚砷酸与元素硫，电位升高到600 mv 附近，亚砷酸被氧化成砷酸，亚铁离 子被氧化成铁离子，在三价铁离子化学浸出的体系，砷黄铁矿阳极氧化反应机理较接种细菌时简单；交流 阻抗研究结果表明，砷黄铁矿电极在有菌体系中反应两天后，沉淀的形成阻碍了电极表面电子传递速率， 使反应阻抗增大；Fe3+化学浸出体系与有菌浸出体系的交流阻抗谱具有相似的特征，在高频端为电极表面 反应动力学控制，低频端为离子扩散控制。 关键词：砷黄铁矿；生物浸出；循环伏安；交流阻抗 Electrochemical study on arsenopyrite biooxidation YUAN Qiuhong, ZHANG Guangji, YANG Chao (Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China) Abstract: The electrochemical behavior of an arsenopyrite electrode for bacterial leaching or 3+ chemical leaching of Fe was studied using cyclic voltammetry and EIS (electrochemical impedance spectroscopy) techniques. The cyclic voltammetry curves show that arsenopyrite was first decomposed to H AsO and element sulfur at potential about 50 mv/SCE in Leathen media 3 3 2+ inoculated with Thiobacillus ferrooxidans. Then the H AsO was oxidized to H AsO and Fe 3 3 3 4 3+ was oxidized to Fe with the increase of potential (E600 mv/SCE). The anode dissolving 3+ mechanism of arsenopyrite was much simple with the chemical leaching of Fe . The electrochemical impedance spectroscopy results indicate that a