萃取电反萃复合技术提取柠檬酸研究.pdfVIP

L028 萃取－电反萃复合技术提取柠檬酸 吕阳成 易莎莎 骆广生 （清华大学化学工程系 化学工程联合国家重点实验室，北京 100084 ） 摘 要 本文开展了萃取－电反萃复合技术提取柠檬酸的实验研究。以7301 为萃取剂，考察了柠檬酸 在油水两相的分配情况、油水分散体系的导电特性以及电渗析过程的电流效率和能耗。结果表明，络 合萃取能够从稀水溶液中充分提取柠檬酸，分散体系电渗析则可高效地将柠檬酸从负载溶剂中进一步 转移浓缩至水相；该过程的电流效率可接近 100%，单位传质能耗可降至2.50 kWh·kg-1 左右，浓缩后 的产液浓度可达1.6M 以上，产液中溶解的微量溶剂可以通过活性炭吸附法去除。 关键词 柠檬酸 分散体系电渗析 络合萃取 复合技术 中图分类号：TQ028.8 文献标识码：A 文章编号： USING COUPLING PROCESS OF EXTRACTION AND ELECTRO-EXTRACTION TO EXTRACT CITRIC ACID LU Yangcheng, YI Shasha, LUO Guangsheng (Department of Chemical Engineering, State key lab of Chemical Engineering, Tsinghua University, Beijing, 100084, China) Abstract The coupling process of extraction and electro-extraction was used in extraction and concentration of dilute citric acid aqueous. 7301/n-octanol selected as solvent, distribution of citric acid in oil water system, conductive characters of disperse system, and currency efficiency and energy consuming of electrodialysis were studied. The results showed complexation extraction was a proper method to extract citric acid from dilute aqueous, and using the disperse system electrodialysis could realize transfer and concentration of citric acid to aqueous phase in further. In disperse system electrodialysis, the currency efficiency near 100%, the energy consuming about -1 2.50 kWh·kg and acceptor concentration above 1.6M could be reached in optimized condition, while trace solvent dissolved in which may be removed by active carbon adsorption. Key words disperse system electrodialysis, citric acid, complexation extraction, coupling process 柠檬酸是一种重要的化工原料，在食品、医药、化妆品、洗涤剂、金属清洗等行业都有 广泛的应用[1] 。柠檬酸主要采用发酵法制备，是世界上以生物化学方法生产产量最大的有机 酸[2] 。柠檬酸发酵液成分复杂，包括菌体、残糖、蛋白质、色素、胶体、无机