异丙醇_水_碱_乙二醇物系常压汽液平衡数据的测定.pdfVIP

∀ 44 8∀ PETROCHEM ICAL T ECHNO LOGY 2006 35 5 - - / , , ( , 3 100 32) [ ] , - - ( ) /, , ( ) /, V ( ) V ( - ) 0. 5 1, 1 1, 2 1, ( ) /- , - ; 80% , ( ) /- / W ilson , 0. 02 [ ] ; ; ; ; ; ; [ ] 1000- 8144 ( 2006) 05 - 0448- 04 [ ] T Q 013. 1 [ ] A V aporL iquid Equ ilibrium of Isop ropanolW aterA lkali/G lycol System at A tm osph eric Pressure Z eng N i, Zhang Songhong, Yao K ejian ( S tate K ey L aboratory B reedin g B ase of G reen C hem istry Syn th esis T echno logy, C o llege of C hem ical Eng ineering and M ateria ls Science, Z hej iang U n iv ersity of T echnology, H angzhou Z hejian g 3 10032, Ch in a) A bstract] V apo rliqu id equ ilibrium ( V LE ) of isoprop ano lw a tera lka li/ g lyco l system w as m ea sured at atm o spheric pressure. The alka li referred to po tassium hydrox ide or sod ium hydrox ide o r po tassium acetate. In the abov e sy stem, g lyco l conta in ing po tassium hydrox ide or sod ium hydrox ide o r po tassium acetate fo rm ed a com posite so lv ent. T he vo lum e ratio s o f com po site so lvent to isopropano lw ater w ere 0. 5 1, 1 1 and 2 1, respective ly. T herm odynam ic con sistency fo r exp ermi enta l da ta o f isopropano l w a ter system w as conf irm ed by m ean s o f H ering ton m ethod. A zeo trop ic po int o f isopropano lw ater co uld be e lmi inated by adding com po site g lyco l so lvent conta in ing po ta ssium hydrox ide