固体溶质在含夹带剂超临界CO2+中相平衡研讨.pdfVIP

A018 固体溶质在含夹带剂超临界CO 中相平衡研究 2 × 金君素 张泽廷 李颖 于恩平 (北京化工大学化学工程学院，北京 100029) 摘 要 用流动法测定了苯甲酸在 328.15K, 8.0-23.0MPa 条件下，在超临界 CO2 和含乙酯、乙醇 或乙酯＋乙醇（摩尔比 1：1）夹带剂的超临界CO2 中的溶解度数据,夹带剂的浓度为 2.0 mol ％； 测定了对羟基苯甲酸丙酯在 308.15K, 8.0-23.0MPa 条件下，在超临界 CO2 和含环己烷、丙酮或环 己烷＋丙酮（摩尔比 1：1）夹带剂的超临界CO2 中的溶解度数据，夹带剂的浓度为3.5 mol ％。 分析了压力对溶解度的影响；讨论了纯溶剂和混合溶剂作夹带剂时，对溶质溶解度的提携作用。 用改进的 Chrastil 方程关联实验数据，计算值与实验值较吻合，相对平均偏差分别为 8.43％（乙酸 乙酯）、9.05 ％（乙酸乙酯＋乙醇）、5.93 ％（乙醇）、5.69 ％（环己烷）、3.55 ％（环己烷＋丙酮）， 4.18 ％（丙酮) 。 关键词 超临界 CO2 夹带剂 固体 溶解度 STUDY ON PHASE EQUILIBRIUM OF SOLID SOLUBILITY IN SUPERCRITICAL CO2 WITH COSOLVENT × JIN Junsu，ZHANG Zeting ，LI Ying and YU Enping (Department of Chemical Engineering，Beijing University of Chemical Technology ，Beijing 100029 ，China) Abstract The solubilities of benzoic acid were measured in supercritical carbon dioxide without and with cosolvents, ethyl acetate ，ethanol or ethyl acetate + ethanol (molar ratio 1:1)，at concentration of 2.0 mol % and 328.15K and pressures from 8.0 to 23.0 MPa, while the solubilities of propyl p-hydroxybenzoate were measured in supercritical carbon dioxide without and with cosolvents, cyclohexane, cyclohexane + acetone, acetone (molar ratio 1:1), at concentration of 3.5 mol % and 308.15K and pressures from 8.0 to 23.0 MPa. The data were obtained by using a flow-type phase equilibrium apparatus. The influence of pressure on the solid solubility were analyzed. The enhancement of solubility was discussed on different pure and mixed