嗜酸嗜热菌FDCU对黄铜矿的生物氧化作用研究.pdfVIP

H029 嗜酸嗜热菌FDCU 对黄铜矿的生物氧化作用 林晖 李聪颖 孟春 郭养浩 （福州大学化学化工学院，福建福州 350002 ） 摘 要 本工作研究嗜热布氏酸菌（FDCU 菌）对难处理梅州黄铜矿的生物浸矿过程特性。FDCU 菌具有很强的氧化浸出硫化矿的能力，对梅州黄铜矿的浸出速率是T.F 菌的 16 倍，具有潜在的 工业应用价值。实验通过系列浸矿体系的比较，初步探讨FDCU 菌的生物浸矿机理。梅州黄铜矿 的浸出，主要是通过FDCU 菌的直接攻击起作用，Fe3+ 的化学浸出作用较弱，细菌氧化浸出速率 是Fe3+化学氧化速率的6 倍。FDCU 菌的吸附过程为快速平衡的过程，符合朗缪尔等温吸附平衡 8 关系。在梅州黄铜矿上的吸附平衡时间约为20min ，最大吸附量XAm 为5.00×10 cells/g-矿，吸附 平衡常数KA 为5.88×10-7ml/cells 。 关键词 FDCU 菌 生物浸矿 黄铜矿 梅州黄铜矿 嗜酸嗜热菌 STUDY ON CHARACTERISTICS OF BIOLEACHING PROCESS BY THERMOPHILIC FDCU SUBSTRATE LIN Hui, LI Congying, MENG Chun, GUO Yanghao (College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 35002,China) Abstract The characteristics of bioleaching processes for refractory MeiZhou chalcopyrite by FDCU were studied in this work. FDCU processed a strong leaching capacity for sulfide ores. In comparison with the mesophile T. ferrooxidans, the concentration of leached copper from MeiZhou chalcopyrite by FDCU was 16 times that by T. ferrooxidans. FDCU had a potential worth for industrial application. The mechanism of bioleaching by FDCU was studied through a series of leaching experiments. The bioleaching of MeiZhou chalcopyrite was carried out through the direct bacterial oxidation by absorbed cells, the indirect chemical leaching was insignificant, the bioleaching rate was 6 times the chemical leaching rate of ferric iron. The adsorption of FDCU was a fast equilibrium process, and was correlated with th Langmuri isotherm. The adsorption of FDCU onto MeiZhou chalcopyrite attained equilibrium within the first 20min of exposure to chalcopyrite particles, the maximum adsorption capa