克百威光催化降解动力学的研究 Parameters effect on photocatalytic degradation kinetics of carbofuran in TiO2 aqueous solution.pdfVIP

中国环境科学2013，33(1)：82-87 ChinaEnvironmentalScience 克百威光催化降解动力学的研究 阳 海P，周硕林1，_，尹明亮1，皮露露1，一，曾健1，易 兵1(1．湖南工程学院化学化工学院，湖南湘潭 41I 104；2．湖南师范大学化学化工学院，湖南长沙410081) 摘要：采用n02光催化技术对克百威的降解进行了研究，并系统地考察了催化剂用量，溶液初始pH值，底物浓度，活性氧物种和各种阴阳离 制作用． 关键词：克百威；光催化降解：活性氧物种；阴离子；金属阳离子 中圈分类号：X592 文献标识码：A 文章编号：1000—6923(2013)O卜0082一06 ParameterseffectOn kineticsofcarbofuranin solution．YANGHai”． degradation Tie2 photoeatalytic aqueous ZHOU of and Chemical Shuo-lin“，YINMing·lian91，PILu·lu“，ZENGJianl，YIBin91(1．CollegeChemistry Instituteof 4111 of andChemical Engineering,HunanEngineering,Xiangtan04．China；2．CollegeChemistry HunanNormal Environmental University,Changsha410081，China)．ChinaScience，2013，33(1)：82-87 ofcarbofuranhasbeen in solutionunderUVirradiation． Abstract：Photoeatalyticdegradation Ti02 investigatedaqueous 111eeffectsofvarious as such of oxidative parameterscatalyst value，concentrationcarbofuran,reactive amount，pH anionsandmetalcationson kineticswerestudied．111e of species(Ross)，different photocatalyticdegradation degradation carbofumnfollows first-orderkinetics model．Theresultsindicatedthattheweak pseudo byusingLangmuir-Hinshelwood alkaline solutionWasfavorforthe ofcarbofuran．The·OHradicaliS forthe of degradation responsiblemajordegradation itscontributionisabout theotherReSsaminor to carbofuran,and