MD膜驱剂与阳离子表面活性剂混合体系的胶束性质研究.pdfVIP

全国第十三次工业表面活性剂研究与开发会议 MD 膜驱剂与阳离子表面活性剂混合体系的胶束性质 杨莉 ,高芒来 ,刘宏生 ,韩翻珍 ,郑广 ( 中国石油大学(北京)化工学院 重质油国家重点实验室 北京 102249) 摘要:通过电导率法测定临界胶束浓度(cmc) 研究了 MD 膜驱剂的浓度 温度及不同无机盐对 MD 膜驱剂与十二烷基三甲基溴化铵(DTAB) 混合体系 cmc 的影响 研究表明 MD 膜驱剂与 DTAB 混合后可降低DTAB 的cmc 并且cmc 随着MD 膜驱剂浓度的增加而减小 温度从25 -1 升高到 50 时 4mmol·L MD 膜驱剂/DTAB 混合体系的 cmc 增大 无机盐的加入有利于混合 体系 cmc 的降低 相同价态的阴离子对cmc 的影响相近 高价阴离子降低cmc 的效果好于低 价阴离子 关键词:MD 膜驱剂 十二烷基三甲基溴化铵 电导率 临界胶束浓度 中图分类号 文献标识 文章编码 The Micellar Property of MDFFA and Cationic Surfactant Mixed System YANG Li ,GAO Mang-lai ,LIU Hong- sheng ,HAN Fan- zhen ,ZHENG Guang (State Key Laboratory of Heavy Oil Processing , Faculty of Chemical Engineering , China University of Petroleum , Beijing 102249 , China) Abstract :Critical micelle concentration (cmc) of Molecular Deposition Filming Flooding Agent (MDFFA) and dodecyltrimethylammonium bromide (DTAB) mixed systems were determined by conductivity method. Effect of concentration temperature and inorganic salts were investigated. The results showed that MDFFA can decrease the cmc of DTAB, the cmc decrease with increasing the concentration of MDFFA. With the increase of temperature from 25 to 45, the cmc of 4mmol·L-1 -1 MDFFA/DTAB mixed system increased. Salt can decrease the cmc of 4mmol·L MDFFA/DTAB. The influence of anionic ions with same chemical valence on the cmc of mixed system was similar, and anionic ions with high valent which decrease the cmc of mixed system are better than anionic ions with low valent. Key words: