高效环保新型原油脱钙剂的研制研究.pdfVIP

C042 高效环保新型原油脱钙剂的研制 1 1 1 2 2 2 汪晓东 朱建华 刘红研 叶明 于洋 张世杰 (1 石油大学化工学院，北京102200，2 中国石油辽河石化分公司，辽宁 盘锦 124012) 摘 要 以新疆混合原油为实验对象，利用分子设计原理，从络合脱钙机理的研究入手，研制出 高效、环保的新型脱钙剂WA ，克服了现有原油脱钙剂适用性差、用量大，且含有对水体造成二 次污染的磷类物质等缺点。研究结果表明，对新疆混合原油的脱钙率大于80%，对新疆混合原油 中Ca、Fe 、Mg 、Cu 等金属元素的总脱除率近 60%，能够满足原油脱金属的要求。同时经WA 处理后的原油粘度、密度和灰分均有所降低，可部分改善原油品质，有利于原油的后续加工。利 用正交试验考察了反应温度、反应时间、加剂量、脱钙剂溶液pH 值等影响脱钙效果的主要因素， 为工业应用提供了有价值的工艺参数和指导。 关键词 原油 多元络合物 脱钙剂 部分改质 中图分类号：TE624 DEVELOPMENT OF DECALCIFYING AGENT FOR CRUDE OIL WITH CHARACTERISTICS OF HIGHLY-EFFICIENT AND ENVIRONMENT-FRIENDLY WANG Xiaodong, ZHU Jianhua and LIU Hongyan (College of Chemical Engineering, Petroleum University, Beijing 102200) YE Ming, YU Yang，Zhang Shi-jie （Liaohe Petrochemical Branch Co., PetroChina, Panjin, Liaoning 124012 ） Abstract In this paper the development of the decalcifying agent for crude oil with characteristic of highly efficient and environment-friendly was presented. The investigation into the mechanism of the decalcifying agent with the metal elements in crude oil indicates that the stability of multi-component complex is more than that of simple complex. Based on this theory we could develop the new type of decalcifying agent, which can remove the oil-soluble organic calcium salt from Xinj iang mixed crude oil in the laboratory scale efficiently. The influence of reaction temperature, reaction time, pH of aqueous solution of decalcifying agent and the dosage of decalcifying agent on the decalcifying efficiency has also been determined. The experimental results demonstrate that the reaction temperature, 第一作者：汪晓东，女，硕士，现在中国石油化工与销售公司工作； 联 系 人：朱建华, 男，教授，博导。 1 reaction time, pH