环氧树脂蒙脱土纳米复合材料的结构与性能研讨.pdf

高电压与绝缘技术 ·1509 · 环氧树脂/蒙脱土纳米复合材料的结构与性能研究 郭 宁 高俊国 张晓虹 哈尔滨理工大学电气与电子工程学院 哈尔滨 黑龙江 150040 【摘 要】 以双酚 A 型环氧树脂为基体树脂，有机化的蒙脱土为 改性剂，以甲基纳迪克酸酐为固化 剂，分别采用溶液插层法与熔融插层法制备了不同蒙脱土含量的环氧树脂/ 蒙脱土复合材 料。利用 X 射线衍射法测试了剥离前后蒙脱土的层间距。用扫描电子显微镜（ SEM）观察 了试样的冲击断口形貌，研究了该复合材料的两相结构。采用热重法（TGA ）测定了试样 的热分解温度，并对其热稳定性进行了对比。结果表明，无论是溶液插层法还是熔融插层 法，均能制得剥离型环氧树脂/ 蒙脱土纳米复合材料。热重分析结果发现，复合材料的热 分解温度并没有随着蒙脱土含量的增加而增加，而是表现出更为复杂的发展趋势。 【关键词】 环氧树脂 PLS 纳米复合材料 相结构 热稳定性 Investigation of Structure and Properties of Epoxy/MMT Nanocomposite Guo Ning Gao Junguo Zhang Xiaohong College of Electrical and Electronic Engineering ，Harbin University of Science and Technology ， Harbin 150040 ，Heilongjiang ，China Abstract ：Epoxy/organic-montmorillonite nanocomposites with different contents of inorganic particles were prepared by diglycidyl ether of bisphenol A ，with surface modified montmorillonite as modifying agent through solvent intercalation and melting intercalation processes ，respectively. Methylenadic anhydride will play a curing role in this system. The intergallery distance of montmorillonite was measured by X-ray diffraction before and after exfoliation. The interphase morphological character of the fracture surface on specimen was characterized by scanning electric microscopy. Thermogravimetric analyses were carried out to estimate the thermal performance of the composites. Some conclusions were drawn by analyzing the results received from all of the tests. Exfoliated composites could be prepared via a solvent intercalation process ， either a melt int