玻璃微珠填充聚丙烯力学性能的实验研讨.pdfVIP

玻璃微珠填充聚丙烯力学性能的实验研究 张立新， 励争， 徐杰， 傅缤 （北京大学力学与工程科学系，北京 100871 ） 摘要: 本文针对玻璃微珠填充聚丙烯聚合物复合体系，首先研究了材料在不同界面粘结状态 下的宏观拉伸、冲击力学性能，并在电镜观测的基础上，讨论了界面改性对于体系抗断裂性 能的影响和增韧机制。采用在位拉伸的实验方法，观测了该复合材料在一维应力作用下，刚 性粒子和基体的界面脱粘、开裂的过程，通过对比改性前后界面的损伤破坏现象，分析了界 面改性的作用效果和细观结构对材料宏观力学性能的影响。本文的工作为发展新型复合材料 提供了实验依据。 关键词: 填充聚合物；在位拉伸；力学性能 Experimental Analysis of Mechanical Properties * about the Glass Bead-filled Polypropylene Zhang Lixin, Li Zheng, Xu Jie, Fu Bin (Department of Mechanics and Engineering Science, Peking University, Beijing 100871) Abstract: In this paper, mechanical properties of rigid particle filled polymers, glass bead-filled polypropylene with different interfacial designs are studied through experiments. Firstly, tensile and impact experiments are carried out, the mechanical performances before and after the interfacial modification by the use of coupling agent are compared. In addition, based on the SEM observation, discussions on the failure and toughening mechanism of the composites are presented, which betrays the destructing mode of the composite varys with different interface intensity, and the modification gives rise to the the dynamic fracture resistant ability. Then the relations between mesoscopic structures and the macro tensile behaviors are investigated by the in situ tensile experiments, in which the application of interfacial modifier is proved to be the most important factor, and the influence on the interface disbonding in the mesoscopic point of view as well as the macroscopical yielding process of the material are analyzed. The results of this paper provide experimental guidance for developing new polymer composites. Key words: filled polymer, in situ tensile experiment, mecha