煅烧时间对低浓度工业钛液制备锐钛型颜料钛白的影响研究-钢铁钒钛.pdfVIP

第33卷第5期 钢摇 铁摇 钒摇 钛 Vol郾33,No郾5 2012年10月 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 IRON STEEL VANADIUM TITANIUM 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 October2012 苏收收收收收收苏收 收 钒钛提取苏 苏收收收收收收 煅烧时间对低浓度工业钛液制备锐钛型 颜料钛白的影响研究 田从学,黄双华,杨摇 颖,任小青,李摇 珲,杨摇 成 ( 攀枝花钒钛检测实验室,四川 攀枝花617000) 摘摇 要:以低浓度工业硫酸钛液为原料,通过水解、洗涤、盐处理、煅烧工艺制备锐钛型颜料钛白,考查了高温段保 温时间对钛白粒子结构及颜料性能的影响,并采用XRD、粒度测试、SEM及颜料性能检测对煅烧样品进行了表征。 结果表明:煅烧条件对钛白粒子的晶体结构、晶粒尺寸、粒子大小及分布和颜料性能等影响显著,粒子大小维持在 300 nm左右,随煅烧保温时间延长晶粒生长满足一级动力学生长模型。 高温段930 益保温30 min为最佳条件,所 制钛白形貌规整,粒度分布最窄,消色力指标达1450,相对白度100郾23%,优于PTA120标样。 关键词:锐钛型颜料钛白;低浓度钛液;水解;煅烧时间 中图分类号:TQ621.1,TF803郾2摇 摇 文献标识码:A摇 摇 文章编号:1004-7638(2012)05-0001-05 Calcination Time Effects on Anatase White Pigment Production via Low Concentration Industrial Titanyl Sulfate Solution Hydrolyzing Tian Congxue,Huang Shuanghua,Yang Ying,Ren Xiaoqing,Li Hui,Yang Cheng (Panzhihua Vanadium Titanium Testing Laboratory,Panzhihua617000,Sichuan,China) Abstract:Using low concentration industrial titanyl sulphate solution as raw material, anatase titania white pigment was prepared viathe sulphateprocessof hydrolyzing,washing,salt treatment and calcina鄄 tion. And the effects of calcinations holding time at the highest temperature on structure and pigment propertieswere investigated. The as鄄prepared calcined sampleswere characterized by XRD,particle size distribution test,SEM and pigment properties test. Calcinations conditions had great influence on the crystal structure,grainsize,particlesizeanditsdistribution,aswellaspigmentpropertiesoftheanatase white pigment. The average particle size of all the samplesmaintained about300 nm,and crystal growth was consistent with first order kinetics of growth model. Keeping temperature at 930 益 for 30 min was the optimized calc