氟橡胶改性乙丙橡胶并用胶的热稳定性.pdf

物理化学学报(Wuli Huaxue Xuebao) 1100 A cta Phys. Chim. Sin., 2008, 24(6) ：1100-1104 June [Note] 氟橡胶/改性乙丙橡胶并用胶的热稳定性 王亚明 刘 岚* 罗远芳 贾德民 ( 南理工大学材料科学与工程学院, 广州 510641) 摘要: 采用热分析技术考察了氟橡胶及氟橡胶(FPM)/改性乙丙橡胶(MEPDM)并用胶在氮气中的热稳定性, 通 过微分法与积分法两种动力学方法计算出了FPM 及FPM/MEPDM 并用胶的热分解活化能E 和指前因子A . 结 果表明, 并用胶的热分解温度稍高于纯的氟橡胶, 但热分解活化能略低于氟橡胶, FPM 、FPM/MEPDM(5%)和 FPM/MEPDM(10%)的热分解活化能分别为251.74、244.98 和219.60 kJ ·mol-1; 热分解反应级数n 均为0.95. 随着 失重百分率的增大, 热分解活化能增大. 关键词: 氟橡胶; 并用胶; 热稳定性 动力学 中图分类号: O642; TB383 Thermal Stability of Fluoroelastomer/MEPDM Blends WANG Ya Ming LIU Lan* LUO Yuan Fang JIA De Min (College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, P. R. China) Abstract: The thermal degradation behaviors of fluoroelastomer and the blends of fluoroelastomer/MEPDM were investigated by thermogravimetry (TG) and derivative thermogravimetry (DTG). The kinetic parameters were evaluated by differential method and integral method. The results showed that the fluoroelastomer/MEPDM blends had higher thermal degradation temperature, but smaller apparent activation energy E than FPM, the E values were 251.74, 244 .98 , and 219 .60 kJ ·mol-1 for FPM , FPM/MEPDM (5%), and FPM/MEPDM ( 10 %) , respectively . The thermal decomposition reaction order was 0.95 for both FPM and FPM/MEPDM blends. The thermal decomposition apparent activation energy E increased with increasing mass fraction loss . The TG and DTG results suggested that the FPM/