有机无机杂化太阳能电池中常见无机缓冲层材料的研究进展.pdfVIP

化 学 学 报 综述 Review ACTA CHIMICA SINICA DOI: 10.6023/ 有机无机杂化太阳能电池中常见无机缓冲层材料的研究进展 叶森云 刘志伟 卞祖强* 黄春辉 (北京大学化学与分子工程学院 北京 100871) 摘要 有机无机杂化太阳能电池中, 电极缓冲层的选择对光电转换效率有着重要的影响. 理想的负极缓冲层兼具传输 电子和阻挡空穴的作用, 而理想的正极缓冲层兼具传输空穴和阻挡电子的作用. 常见的无机电子传输材料主要有TiO2 和ZnO 等, 而常见的无机空穴传输材料主要有CuI、CuSCN 和NiO 等. 本文就这些常见的无机缓冲层材料在有机无机 杂化太阳能电池中的应用作一简要回顾, 并对其可能存在的问题进行了分析和评述. 关键词 缓冲层; 有机无机杂化; 太阳能电池 Research Progress on Inorganic Buffer Layer Materials in Organic-Inorganic Hybrid Solar Cells Ye, Senyun Liu, Zhiwei Bian, Zuqiang* Huang, Chunhui (College of Chemistry and Molecular Engineering , Peking University, Beijing 100871) Abstract Organic-Inorganic hybrid solar cells combine the advantages of organic and inorganic semiconductors, and pos- sess promising application prospect. Although the active layer in hybrid solar cells is the most important, the electrode buffer layers, including cathode buffer layer and anode buffer layer, have a great influence on the power conversion efficiency (PCE) of the cells. Inorganic semiconductors are often used as the electrode buffer layers because of their high chemical sta- bility, high carrier mobility, and high transparency. TiO and ZnO are the most widely used inorganic electron transport layer 2 materials while inorganic hole transport layer materials, such as CuI, CuSCN and NiO, have been applied frequently in or- ganic-inorganic hybr