外加压应力对纯Ni在800℃空气中氧化行为的影响-中国有色金属学报.PDFVIP

19 12 2009 12 Vol.19 No.12 The Chinese Journal of Nonferrous Metals Dec. 2009 1004-0609(2009)12-2162-05 Ni 800 ( 116024) (TGA)Ni 800 10 20 MPa Ni Ni 800 NiO / Ni TG172.82 A Effect of compressive stress on oxidation behavior of pure nickel at 800 in air ZHOU Chang-hai, MA Hai-tao, WANG Lai (School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, China) Abstract: The effect of compressive stress on the oxidation behavior of pure nickel was investigated by thermogravimetric analysis (TGA). Compressive samples were subjected to stresses of 10 and 20 MPa and the oxidation behavior was studied at 800 in air. The surface and cross section morphologies of the oxidized coating were analyzed by SEM. The change of oxidation kinetic and the failure form of the coatings under compressive stress were analyzed. The effect of compressive stress on the oxidation behavior of pure nickel at high temperature was discussed. The results show that the compressive stress increases the oxidation rate, which is attributed to the effect of compressive stress on the oxidized coating microstructure. Compared with the formation of ridge-like oxide, the compressive stress deduces the formation of particles oxide of NiO, which increases the short-circuit paths for diffusion. In addition, the compressive stresses induce vacancies coalescence at oxide-metal interface