二段中和法处理酸性矿山废水-中南大学学报.PDFVIP

42 5 () Vol.42 No.5 2011 5 Journal of Central South University (Science and Technology) May 2011 1, 2 1, 2 2 (1. 410083 2. 527300) pH 5 FeMn Zn 14.14%5.94% 13.91%pH 10.20 50 mL/min20 min 99.7%TFe Mn2+Zn2+ 8081030 µg/L(GB (CaSO ·2H O) (Fe Mn Zn O ·nH O)(Fe O ) 4 2 2 0.5 0.5 4 2 3 4 X703.1 A 1672−7207(2011)05−1215−05 Treatment of acid mine drainage by two-step neutralization ZHENG Ya-jie1, 2, PENG Ying-lin1, 2, LI Chang-hong2 (1. School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China; 2. Yunfu Institute of Central South University, Yunfu 527300, China) Abstract: The acid mine drainage was treated by two-step neutralization method using lime and sodium hydroxide. The results show that the removal rates of total iron (TFe), Mn and Zn are 14.14%, 5.94% and 13.91%, respectively, when the pH of the wastewater is adjusted to about 5 with lime. In the second step, using sodium hydroxide as neutralizing agent, when pH is 10.20, airflow is 50 mL/min, reaction time is 20 min, the removal rates of TFe, Mn and Zn are all up to 99.7%, and the residual contents of TFe, Mn and Zn are 80, 810 and 30 µg/L, respectively in wastewater, which are below the Chinese standards of wastewater discharge (GB. The first-step slag product treated by lime neutralizing is gypsum (CaSO ·2H O). The second-step slag products treated by sodium hydroxide neutralizing are Fe Mn Zn O ·nH O