功能材料rGO TiO2复合光催化剂的合成与研究.pdfVIP

Material Sciences 材料科学, 2017, 7(9), 811-821 Published Online December 2017 in Hans. /journal/ms /10.12677/ms.2017.79105 Preparation and Study on Composite Photocatalysts of rGO/TiO2 Function Materials * * Gaimei Li, Shudan Li , Xiuhua Wang, Kun Gao School of Chemistry and Materials Science, Shanxi Normal University, Linfen Shanxi th st th Received: Dec. 4 , 2017; accepted: Dec. 21 , 2017; published: Dec. 29 , 2017 Abstract In this paper, rGO/TiO2 composites with different amount of graphene were controllably synthesized by alkaline one-step hydrothermal method (the content of graphene is 0%, 1%, 5%, 10% and 15%). By XRD, SEM, Raman, Nitrogen adsorption-desorption and photocatalytic degra- dation of methylene blue solution (MB), we explored the effect of graphene and its contents on op- timizing TiO2 structure, morphology and photocatalytic activity. The results indicated that: (1) GO was reduced to thin-flake graphene in the strong alkaline hydrothermal reaction. Besides, the doping of graphene did not change the crystalline phase structure of TiO2, but resulted in the de- crease of particle size and increase of surface area when it comes to composites. Secondly, it also reduced the diffusion and transfer impedance of electrons. (2) Appropriate amount of graphene not only enhanced the effective contact between pollutants and photocatalysts, but also can be used as electron acceptor to promote the separation of electron-hole of TiO2, thus improving the photocatalytic activity of TiO2. (3) But excessive graphene would be able to covered partial ac-