生物脱氮—原理及工艺PPT.pptVIP

生物脱氮工艺 Step-feed Process A1 An2 A2 An3 A3 An4 A4 Return Sludge (r), NO3- An1 Qin, TNin, CODin f1*Qin f2*Qin f3*Qin f4*Qin * * * * * * * * * * * * * * * * * * 污水深度处理与回用 (2)生物脱氮—原理及工艺 污水中氮的存在形式 Subdivision of Nitrogen in Wastewater (Influent) COD related SI*iN,SI (~3%) SA: 0 SF: iN,SF=0.03 gN/gCODSF SI: iN,SI=0.01 gN/gCODSI XS: iN,XS=0.03 gN/gCODXS XI: iN,XI=0.04 gN/gCODXI XI*iN,XI (~10%) SF*iN,SF+XS*iN,XS (~12%) iN,BM=0.07 gN/gCODBM Nitrogen Removal: N in Wastewater→N2 (into atmosphere) 氮的转化途径 Nitrogen Conversion Pathways (N Cycle) 生物脱氮过程 Nitrification and denitrification NH3 NO2 NO2 NO3 -3 -2 -1 0 +1 +2 +3 +4 +5 Denitrification N-fixation Nitrification N2 生物脱氮过程 Nitrification NH4+ NO2- NO3- NO2- NO(g) N2O(g) N2(g) Denitrification Aerobic (DO); Autotrophic Anoxic; Heterotrophic (Organic Carbon) tG=ln2/μmax 生物脱氮过程 硝化反应—动力学（Kinetics） Growth Rate: ? Decay Rate : ? Net Growth Rate: ? XA: Nitrifiers Concentration (mg VSS?L-1); μ: Specific growth rate of nitrifiers (d-1); μmax: Maximum specific growth rate of nitrifiers (d-1); SNH: Ammonium-N concentration (mg?L-1); KNH: Half saturation coefficient for ammonium (mgN?L-1); bA: Decay rate of nitrifiers (d-1) mg VSS/(L?d) mg VSS/(L?d) mg VSS/(L?d) 生物脱氮过程 硝化反应—影响因素（Factors Influencing Nitrification） (1). Minimum SRT Waste Sludge Qw, Xr Effluent Influent Secondary clarifier Aeration basin Q Qeff, Xeff X, V Sludge Return Qr, Xr ? (Days) Sludge Wastage Rate = XA/SRT (mg VSS/(L?d)) 生物脱氮过程 硝化反应—影响因素（Factors Influencing Nitrification） (1). Minimum SRT Waste Sludge Qw, Xr Effluent Influent Secondary clarifier Aeration basin Q Qeff, Xeff X, V Sludge Return Qr, Xr Net Growth Rate ≥ Sludge Wastage Rate ? ? ? ? ? 生物脱氮过程 硝化反应—影响因素（Factors Influencing Nitrification） (1). Minimum SRT ? At steady state: ? ? ? T=20 μmax=0.4/d bA=0.04/d KNH=1 mg N/L SRTmin Question: 1) Calculate SRTmin; SRT for SNH=1 mg/l. 生物脱氮过程 硝化反应—影响因素（Factors Influencing Nitrification） (2). Temperature ? ? For every 6°C drop, the value will halve. Des