利用烧结脱硫灰渣制备新型充填胶凝材料试验杨志强12熊良锋1方.DOCVIP

利用烧结脱硫灰渣制备新型充填胶凝材料试验 杨志强1, 2 熊良锋1 方 林1 高 谦1( 田立鹏1 （1 北京科技大学 土木与环境工程学院 北京 100083 2 金川集团股份有限公司 甘肃 金昌 737100） 摘 要：烧结脱硫灰渣是半干法脱硫排放的废弃物。灰渣含有亚硫酸钙和飞灰等不稳定矿物成分，使得该废弃物利用面临困难。针对铁矿全尾砂胶结充填法采矿对廉价的胶凝材料的需求，采用烧结脱硫灰渣和水淬渣，开展了制备全尾砂充填胶凝材料试验研究。以生石灰作为碱激发剂，硫酸盐作为辅助激发剂，对矿渣微粉活性实施复合激发。首先采用正交设计进行试验方案设计；然后采用极差分析对数据进行处理和配比决策最后以阶段嗣后充填采矿对其强度要求，建立并求解全尾砂新型充填胶凝材料的优化模型，获得了充填胶凝材料的优化配比。结果显示，以生石灰和烧结脱硫灰渣作为水淬渣复合激发剂制备的新型充填胶凝材料，烧结脱硫灰渣达到10%时，3d、7d及28d的胶结充填体强度不低于相同条件下的32.5R早强水泥，而胶凝材料成本低于水泥材料。 关键词：烧结脱硫灰渣；水淬渣；全尾砂；充填胶凝材料；正交试验；优化配比 Preparation of New Filling Cementing Materials with Sintering Desulfurization Ash YANG Zhi-qiang1, 2 XIONG Liang-feng1 FANG Lin1 GAO Qian1( TIAN Li-peng1 (1 School of Civil and Environmental Engineering, University of Science and Technology Beijing, Beijing 100083, 2 Jinchuan Group Co. LTD, Jinchang Gansu Province 737100) Abstract: The sintering desulfurization ash is the waste produced by a semi dry Flue Gas Desulfurization (FGD) system. The desulfurization ash, which consists of some unstable mineral compositions, such as CaSO3 and f-CaO, is difficult to be used. Considering the demand of cheaper cementing material for filling stoping in iron mine, a new filling cementing material is prepared with sintering desulfurization ash and water-quenched Slag. It is manufactured by a composite activator, which is composed of quicklime and sulfate, while the quicklime is the main activator and the sulfate is an auxiliary excitation agent. Firstly the orthogonal design is adopted and implemented. Then the range analysis is taken and the optimal ratio can be obtained. Finally an optimal model of composite activator ratio is established and solved by the regression analysis. In view of the requirements in filling stoping, the optimal proportion is obtained. It shows that, when the adding amount of the sintering desulfurization ash is up 10%, the mass ratio of the cementing material to tailing being 1:8 and the concentration (by mass) of backfilling slurry being 68%, the strength