Si_3N_4与Si_3N_4_hBN陶瓷配副在水润滑下的摩擦化学行为.pdfVIP

43 9 西 安 交 通 大 学 学 报 Vol. 43 9 2009 9 JOURNAL OF XIAN JIA OTONG UNIVERSITY Sep. 2009 Si N Si N hBN 3 4 3 4 , , , ( , 710049, ) : 利用 MMU5G 销盘式端面磨损试验机考察了蒸馏水润滑条件下 Si3 N4hBN( 六 氮化硼) 复合陶瓷与Si3 N4 陶瓷配副时的摩擦磨损性能, 并分别采用扫描电子显微镜激光扫描显微镜X 光电子能谱和X 射线能谱分析了摩擦面的形貌和物质组成. 结果表明: 在滴定法水润滑条件下, Si3 N4hBN/ Si3 N4 配副的摩擦因数随hBN 含量的增加而显著降低, 当hBN 体积分数为20%时, 摩 擦因数降至001, Si3 N4hBN 的磨损率接近0; 在浸入法水润滑条件下, Si3 N4hBN/ Si3 N4 配副的 3 4 3 4 摩擦因数均降至001. 在滴定法水润滑条件下, 磨屑不易被水带走, 当Si N hBN 与Si N 配副摩 擦时, 由于Si3 N4hBN 摩擦面上hBN 偏聚区域发生脆性断裂和剥落而形成剥落坑, 磨屑在剥落坑 中堆积并氧化水解, 反应产物富集于剥落坑中, 进而在摩擦表面形成含B2 O3 和SiO2 的摩擦化学 反应膜, 从而保护了Si3 N4hBN 和Si3 N4 摩擦面, 使其变得光滑, 为发生流体润滑提供了条件. : 复合陶瓷; 水润滑; 剥落坑; 摩擦化学反应膜 : TH 1171 : A : 0253987X( 2009) Tribochemical Behavior of Si3 N4hBN Ceramic Materials with Water Lubrication CHEN Wei, GAO Yimin, JU Faliang, WAN G Yong ( State Key Laboratory for Mechanical Behavior of M aterials, Xian Jiaotong University, Xian 710049, China) Abstract: The tribological behavior of Si3 N4hBN composites with different hexagonal boron ni tride ( hBN) volume fractions under distilled water lubrication was investigated. Waterlubricated sliding tests were conducted on a pinondisc tester. T he results show that the addition of hBN in to Si3 N4 matrix significantly decreased the friction coefficient from 030 for Si3 N4 against Si3 N4 pair to 001 for Si3 N420% hBN against Si3 N4 pair under titrimetric water lubrication, and the friction coefficient of Si3 N4hBN/ Si3 N4 pair decreased to 001 in water . The morphological analy sis and ch