流化床气化炉半焦细粉水蒸气再气化特性及动力学研究-OALib.PDFVIP

第41卷 第4期 燃摇 料摇 化摇 学摇 学摇 报 Vol.41No.4 2013年4 月 Journal of Fuel Chemistry and Technology Apr. 2013 文章编号:0253鄄2409(2013)04鄄0400鄄07 流化床气化炉半焦细粉水蒸气再气化特性及动力学研究 1,2 1 1 景旭亮 ,王志青 ,房倚天 (1.中国科学院 山西煤炭化学研究所,山西 太原摇 030001;2.中国科学院研究生院,北京摇 100049) 摘摇 要:利用热天平考察了流化床气化炉半焦细粉的水蒸气再气化特性及其动力学,并与相应的自制半焦及脱灰半焦细粉进 行了比较分析。 结果表明,半焦细粉的再气化反应性随着温度的升高而增加。 与自制热解半焦相比,半焦细粉的反应性较 高,这主要取决于比表面积的影响,而不同细粉的气化反应性差异还与其石墨化程度和灰含量有关。 在此基础上,利用缩核 模型对半焦细粉的再气化行为进行了模型拟合并得到了动力学参数,从而为细粉的再气化提供了一定的理论指导。 关键词:半焦细粉;水蒸气气化;孔结构;气化动力学 中图分类号:TQ546摇 摇 文献标识码:A Steam re鄄gasification properties andkinetics of coal char fines derived from fluidized bed gasifier 1,2 1 1 JING Xu鄄liang ,WANG Zhi鄄qing ,FANG Yi鄄tian (1.Institute of Coal Chemistry,ChineseAcademy of Sciences,Taiyuan摇 030001,China; 2.University of ChineseAcademy of Sciences,Beijing摇 100049,China) Abstract:The steam gasification behavior and kinetics of coal char fines derived from fluidized bed gasifier were investigated by TGS鄄2 thermogravimetric analyzer. Their physical and chemical properties were also compared with the corresponding coal charsand demineralized char fines. The results show that the gasification reactivity of char fines increase with increasing temperature. Compared with the coal char from pyrolysis,the char fine hasa larger surface area and leads to a higher gasification reactivity. The reactivity of different coal char finesare also affected by their carbon crystalline structure and ash content. Based on this,the gasification reactionsare described by the shrinking core model and the kinetic parameter