热解解毒铬渣处理水中磷酸盐的应用 Application of Chromium Slag Detoxified by Pyrolysis for Phosphorus Removal in Waste Water Treatment.pdfVIP

热解解毒铬渣处理水中磷酸盐的应用 Application of Chromium Slag Detoxified by Pyrolysis for Phosphorus Removal in Waste Water Treatment.pdf

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热解解毒铬渣处理水中磷酸盐的应用 Application of Chromium Slag Detoxified by Pyrolysis for Phosphorus Removal in Waste Water Treatment

水技术2010 ,29(4 ):44-48 ,70 Water Purification Technology Vol. 29, No. 4, 2010 热解解毒铬渣处理水中磷酸盐的应用 彭亢晋,张大磊,孔海南,吴德意,何圣兵,卜冠华 (上海交通大学环境科学与工程学院,上海 200240 ) 摘 要 采用600 ℃和800 ℃下的两种热解解毒铬渣处理模拟含磷废水,研究了最佳反应条件,并探讨了解毒铬渣除磷的机 理。结果表明,热解解毒后铬渣的浸出毒性大幅降低,当磷浓度为50 mg L 时,选择投加量为2.5 g L ,振荡接触时间为2 h 。磷分 级试验结果表明,解毒铬渣除磷机理主要是溶出金属离子的沉淀作用,从铬渣中溶出的Ca2+ 含量和平衡溶液pH 值对除磷效率 有较大影响,铬渣在碱性条件下处理效果较好,适宜处理中性和碱性含磷废水。 关键词 铬渣 热解 解毒 除磷 资源化 中图分类号:X703.1 文献标识码:A 文章编号:1009-0177(20 10)04-0044-06 Application of Chromium Slag Detoxified by Pyrolysis for Phosphorus Removal in Waste Water Treatment Peng Kangjin, Zhang Dalei, Kong Hainan, Wu Deyi, He Shengbing, Bu Guanhua (School of Env ironmental Science and Engineering, Shanghai Jiao Tong Univ ers ity, Shanghai 200240, China) Abstract The chromium slag which was used to treat the phosphorous waste water was detoxified using pyrolysis technology under 600 ℃and 800 ℃separately. The best react conditions were investigated, besides, the mechanism of phosphate removal was also dis- cussed. The results show that after pyrolysis process, the leaching toxicity of detoxification slag decreased dramatically while the phos- phorous removal capacity increased. When the initial phosphate concentration is 50 mg L, the best dosages are 2.5 g L, with the reac- tion time of 2 h. The result of partition experiment of phosphate is confirmed that the removal of phosphate is mainly due to the mecha- nism of precipitation. The leaching Ca2+ content and pH value has a direct impact on the phosphate removal efficiency. The detoxified slag which worked well in the alkaline condition, is suitable to treat neutral and alkaline phosphorus waste water. Key words chromium slag pyrolysis detoxification phosphate removal recycle 铬渣是金属铬及铬盐生产和铬铁生产过程中排 性较小的Cr( Ⅲ) ;而资源化则是利用铬渣

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