龙岩大气颗粒物中多环芳烃源识别及污染评价 Source Identification and Pollution Evaluation of Polycyclic Aromatic Hydrocarbons in Airborne Particulate.pdfVIP

环境科学研究 第21卷第3期 ResearchofEnvimnmentalSciences Vel．21．No．3．2008 龙岩大气颗粒物中多环芳烃源识别及污染评价 何立芳，章汝平 龙岩学院化学与材料工程系，福建龙岩364000 摘要：采用恒能量同步荧光法，研究了龙岩市区不同功能区冬、春季大气颗粒物中多环芳烃(PAHs)的污染状况和污染来源， 并对不同功能区的PAHs含量进行了评价．结果表明：龙岩市区各功能区大气颗粒物中P(PAHs)为278．95—718．25n∥o，且冬 季高于春季．根据PAHs中一些特征标志物的比值，可判断冬、春季市区内PAHs主要来源于汽车尾气和燃煤污染．采用苯并 [a]芘含量(P(BaP))均超过国家标准(10ng，m3)，且P(PAHs)均严重超标． 关键词：多环芳烃；恒能量同步荧光；大气颗粒物；污染来源；污染评价 中图分类号：X113．1 文献标志码：A 文章编号：1001—6929(2008)03—0007—06 SourceIdentificationandPollutionEvaluationof Aromatic Polycyclic inAirborneParticulate ， HE Li—fang，ZHANGRu·ping of andMaterials 364000，China DepartmentChemistry Engineering，I∞ngyanCollege，Longyan state aromatic wele Abstract：The andsoul∞eof airborne studied constant- pollution polycyclie hydrocarbons(PAH8)inparticulate using fluorescence indifferentfunction in inwinterand the energy synchronous spectrometrytechnique regionsLongyanCity spring，andpollution evaluationofPAHsindifferentfunction total theairborne from278．95to718．25 regions惴made．TheP(PAHs)in particulateranged ng／m’ indifferentfunction of was inwinterthanin onsome indexratiosof City，andhigher diagnostic PAHs，the regionsLongyan spring．Based PAHs ofeachfunction comesfromautomobileemissionandcoal inwinterand benzo[a] pollution regionmainly burningpollution spring．The toevaluatethePAHs stateinthe