激光拉曼光谱PPT.ppt

Liquid and gas inclusions in quartz quartz H2O CO2 CH4 N2 Liquid and gas inclusions in quartz NExT filter spectrum of InAs/GaSb superlattice 633 nm excitation NSOM Raman Imaging Spectrum of potassium titanyl phosphate. From Hans Hallen at NCSU. Squares are 5 x 5 μm square of this material doped with Rb. A near-field scanning microscope was used and the Raman signal was used to key the substrate response. Chemical Mapping Focus laser to small spot. Tune spectrometer to particular Raman transition peak. Raster scan the sample under the laser beam, record intensity changes. Resultant map correlates with substance. Acquire an entire spectrum at every point, then choose the feature with which to key the image. Motorized stage from Renishaw for chemical mapping. This is a drug tablet. The yellow corresponds to the active ingredient. Particles are in the 10’s of μm range. Raman mapping At each point (x,y) Take spectrum Fit curve(s) Use curve parameters to make images area(x,y) etc. I W A Strain mapping of Silicon Width / cm-1 (HWHM) 2.50 2.80 2.70 2.60 50 10 0 20 30 40 μm 1 s exposure per spectrum (51x51=2601 spectra) 50 10 0 20 30 40 μm 522.5 523.0 523.5 Position / cm-1 Intensity / counts 2000 4000 6000 Comparison of mapping imaging Mapping Imaging Spectral resolution 1 cm-1 20 cm-1 Spatial resolution 1?μm 1?μm Depth of field 2 μm Time 8 hours 30 s Chemical Imaging Now defocus the laser (not a small spot but rather “baths” the sample in laser radiation). Pass the emitted radiation through a narrow bandpass filter, adjusted to a particular wavelength, chosen to be a certain Raman band. Focus this light on the CCD camera. Bright regions correspond to locations of substance giving rise to Raman signal. Mixture of cocaine and sugar. Bright spots are cocaine. Raman imaging of quantum dots Raman studies of quantum dots Dry etched GaAs-AlGaAs “quantum” dots Raman imaging of patterned polymer Deposit 16 layer Langmuir-Blodgett film of 12-8 diac