杂质离子对沉淀多钒酸铵的影响-钢铁钒钛.PDFVIP

第34卷第3期 钢摇 铁摇 钒摇 钛 Vol.34,No.3 2013年6月 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 IRON STEEL VANADIUM TITANIUM 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 June2013 杂质离子对沉淀多钒酸铵的影响 杨摇 合,毛林强,薛向欣,刘摇 东 (东北大学材料与冶金学院,辽宁沈阳110819) - 2- 摘摇 要:采用酸性铵盐法沉钒,研究了沉钒液中的杂质离子Cr、P、Si、Cl 、SO4 对钒沉淀的影响。 结果表明:Cr浓度 的增大能够显著降低钒的沉淀率,对低浓度的钒溶液影响更显著;Si对沉钒率影响较小,P对钒的沉淀率有较大影 响,当P浓度大于0.1g/ L时,沉钒率在75%以下;Cl-在低浓度条件下对沉钒率影响不大,但当NaCl浓度大于100 2- g/ L时,沉钒率低于20%;SO 对沉钒率影响不显著。 4 关键词:V O ;酸性铵盐沉淀;多钒酸铵;杂质;沉钒率 2 5 中图分类号:TF841.3摇 摇 文献标志码:A摇 摇 文章编号:1004-7638(2013)03-0013-06 DOI:10.7513/ j.issn.1004-7638.2013.03.003 Effects of Impurities on Ammonium Polyvanadate Precipitating Yang He,Mao Linqiang,Xue Xiangxin,Liu Dong (School of Materials and Metallurgy,Northeastern University,Shenyang 110819,Liaoning,China) - 2- Abstract:Effectsof impuritiessuch asCr,P,Si,Cl and SO on ammoniumpolyvanadateareinvesti鄄 4 gated asammoniumpolyvanadateisprecipitatedwith acidicammonium salt. Theresultsshow thatthein鄄 crease of Cr concentration significantly reducesthevanadiumprecipitationrate,especiallyforthevanadi鄄 2- um liquid with low concentration;Si and SO exert little influence on the precipitation,while P has a 4 noticeable effect as its concentration is above0.1g/ L,the precipitation rate of vanadium isbelow75%; - the e