天然斜发沸石粉对溶液中NH4+的吸附机理研究 Adsorption characteristics of ammonium ions by natural clinoptilolite powder.pdfVIP
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天然斜发沸石粉对溶液中NH4的吸附机理研究Adsorptioncharacteristicsofammoniumionsbynaturalclinoptilolitepowder
中国环境科学201 ChinaEnvironmentalScience
0.30(5):609--614
天然斜发沸石粉对溶液中NH4+的吸附机理研究
张新颖,吴志超‘,王志伟,周 琪,杨殿海(同济大学环境科学与T程学院上海200092)
35%~57%.由于沸石粉粒径较小,其对NH4+的去除除了依靠离子交换作用外,物理吸附作用的贡献不容忽视.
关键词:天然斜发沸石;氨氮;吸附;离子交换;污水处理
中图分类号:X703.1 文献标识码:A 文章编号:1000-6923(2010)05-0609-06
characteristicsofammoniumions natural ZHANG
Adsorption by clinoptilolitepowdec Zhi-chao’,
Xin-ying,WU
WANG and
ofEnvironmentalScience
Zhi·wei,ZHOUQi,YANGDian-hai(School University,
Engineering,Tongji
Environmental
Shanghai200092,China).ChinaScience,2010,30(5):609-614
Abstract:Natural an size selectedas
clinoptilolitepowder,withaverageparticleof30pxn,wasexperimental
characteristicsofthe on solutionwere the ofmetalelements
adsorption clinoptiloliteNH4+in studied,withmonitoring
concentrationin and isothermal kinetics were
liquid—phasesolid-phase.Theadsorptionexperiment,adsorptionexperiment
results anunoniura
conducted.Theshowedthatthe the WasfittedwellwithFreundlich
adsorptionby natul脚clinoptiiolite
the second-order wasless
adsorptionisotherm(群=O.996)andpseudo kinetics僻2:川.99).Theadsorptionprocess
withtheincrease the inthis
favorable ofinitial ofthe amount
NI-h+concentration.Na+,Ca2+occupiedmajorpart exchange
into first.Then amountofCa2j andexceededN《
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