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Diamond and Related Materials 13 (2004) 54–59
Enhancement of field emission from hydrogen plasma processed carbon
nanotubes
a, a a a a b
Jihua Zhang *, Tao Feng , Weidong Yu , Xianghuai Liu , Xi Wang , Qiong Li
aIon Beam Laboratory, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, 865, Changning Road,
Shanghai 200050, PR China
bDepartment of Electronics Science and Technology, East China Normal University, Shanghai 200062, PR China
Received 21 April 2003; received in revised form 23 July 2003; accepted 25 August 2003
Abstract
An effective approach to improve the field emission site density and large area uniformity of carbon nanotube (CNT) films
has been presented. I– V characteristics, Raman spectra, as well as surface morphology and microstructure of the CNT films
before and after the hydrogen plasma process (HPP) were investigated. Results showed that after the HPP nano-nodes appeared
along the tubes and the field electron emission site density increased dramatically from 103 to 106 cmy2 . A model for the
formation of the nodular CNTs was proposed. We attributed this improvement to the changing of the electronic andyor geometrical
structure of the local emission region in CNTs.
2003 Elsevier B.V. All rights reserved.
Keywords: Field emission displays; Carbon nanotubes; Thin films
w x
1. Introduction improve
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