Effect of Dispersion on Adsorption of Atrazine by Aqueous Suspensions of Fullerenes英文文献.pdfVIP
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ARTICLE
/est
Effect of Dispersion on Adsorption of Atrazine by Aqueous
Suspensions of Fullerenes
Ke Gai, Baoyou Shi,* Xiaomin Yan, and Dongsheng Wang
State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing 100085, Peoples Republic of China
S Supporting Information
b
ABSTRACT: With the widespread application of fullerenes, it is critical to
assess their environmental behaviors and their impacts on the transport
and bioavailability of organic contaminants. The effects of fullerene
particle size, chemistry of the solution, and natural organic matter on
the adsorption of atrazine by aqueous dispersions of fullerenes (C60) were
investigated in this work. The results showed that the Polanyi-Manes
model could fit the adsorption isotherms well. Smaller sizes of fullerene
particles led to increased available sites and, consequently, enhanced the
adsorption of atrazine on C60. However, intensely dispersed C60 systems
might not possess suitably high adsorptive capacities due to surface
chemistry change. Adsorption of atrazine by aqueous dispersions of C60
increased with a decrease in the pH of the solution. Introduction of humic
acid significantly reduced the size of the C60 particles, and resulted in the
increase of the adsorption amount. Fullerene materials, once released into the aquatic environment, are inclined to form aqueous
suspensions with different degrees of dispersion, which would greatly affect the transport and fate of organic contaminants.
’INTRODUCTION hydrocarbons (PAHs) onto aqueous suspensions of C60.16 The
Fullerenes (C60) and other carbon-based nanomater
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