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INSTITUTE OF PHYSICS PUBLISHING JOURNAL OF PHYSICS: CONDENSED MATTER
J. Phys.: Condens. Matter 17 (2005) 5697–5708 doi:10.1088/0953-8984/17/37/008
Electron and phonon confinement and surface phonon
modes in CdSe–CdS core–shell nanocrystals
1 2 2 1
A Singha , B Satpati , P V Satyam and Anushree Roy
1 Department of Physics, Indian Institute of Technology, Kharagpur 721 302, WB, India
2 Institute of Physics, Bhubaneswar 751005, India
E-mail: anushree@phy.iitkgp.ernet.in
Received 12 July 2005, in final form 8 August 2005
Published 2 September 2005
Online at stacks.iop.org/JPhysCM/17/5697
Abstract
The optical and vibrational properties of bare and CdS shelled CdSe
nanocrystalline particles are investigated. To confirm the formation of such
nanocrystals in our samples we estimate their average particle sizes and size
distributions using TEM measurements. From the line profile analysis of the
HRTEM images the core–shell structure in the particles has been confirmed.
The blue shift in the optical absorption spectra, analysed using theoretical
estimates based on the effective bond order model, establishes the electron
confinement in the nanoparticles. The main aim of this paper is to show the
unique characteristics of the nanocrystals (which are absent in the corresponding
bulk material), such as confinement of optical phonons and the appearance of
surface phonons. Making use of the dielectric continuum model
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