Electron and phonon confinement and surface phonon英文文献.pdfVIP

Electron and phonon confinement and surface phonon英文文献.pdf

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INSTITUTE OF PHYSICS PUBLISHING JOURNAL OF PHYSICS: CONDENSED MATTER J. Phys.: Condens. Matter 17 (2005) 5697–5708 doi:10.1088/0953-8984/17/37/008 Electron and phonon confinement and surface phonon modes in CdSe–CdS core–shell nanocrystals 1 2 2 1 A Singha , B Satpati , P V Satyam and Anushree Roy 1 Department of Physics, Indian Institute of Technology, Kharagpur 721 302, WB, India 2 Institute of Physics, Bhubaneswar 751005, India E-mail: anushree@phy.iitkgp.ernet.in Received 12 July 2005, in final form 8 August 2005 Published 2 September 2005 Online at stacks.iop.org/JPhysCM/17/5697 Abstract The optical and vibrational properties of bare and CdS shelled CdSe nanocrystalline particles are investigated. To confirm the formation of such nanocrystals in our samples we estimate their average particle sizes and size distributions using TEM measurements. From the line profile analysis of the HRTEM images the core–shell structure in the particles has been confirmed. The blue shift in the optical absorption spectra, analysed using theoretical estimates based on the effective bond order model, establishes the electron confinement in the nanoparticles. The main aim of this paper is to show the unique characteristics of the nanocrystals (which are absent in the corresponding bulk material), such as confinement of optical phonons and the appearance of surface phonons. Making use of the dielectric continuum model

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