Factors Controlling the Formation of Core Shell英文文献.pdfVIP

Chem. Mater. 2006, 18, 4959 Factors Controlling the Formation of CoreShell ZeoliteZeolite Composites Younes Bouizi,† Loı¨c Rouleau,‡ and Valentin P. Valtchev*,† Laboratoire de Mate´riaux a` Porosite´ Controˆ le´e, UMR-7016 CNRS, ENSCMu, Uniersite´ de Haute Alsace, 3, rue Alfred Werner, 68093 Mulhouse Cedex, France, and Institut Francais du Pe´trole, BP3 - 69390 Vernaison, France Recei ed May 18, 2006. Reised Manuscript Receied July 17, 2006 Coreshell zeolitezeolite composites possessing single-crystal cores and polycrystalline shells of different zeolite structure types were synthesized. The formation of an intergrown shell structure was induced by preliminary seeding of the core crystals and subsequent secondary growth under hydrothermal conditions. The utilization of seeds suppressed the influence of framework particularities of the core crystals on the formation of the shell layer. Hence, the couples of zeolitic materials were chosen in a way to reveal the effect of differences between the chemical compositions and crystallization conditions of core and shell zeolites on the formation of the desired composite. The following couples of microporous materials were involved in the investigation: SOD-LTA, BEA-LTA, FAU-MFI, MFI-BEA, and MFI- MFI (ZSM-5silicalite-1), the first structure type representing the core and the second the shell material. Complementary techniques, such as XRD, TG/DTA,