新型干法水泥窑硫动态循环研究.docVIP

新型干法水泥窑硫动态循环研究 鹰1，2 ，杨 康1 ，徐德龙1，2 ，周 蕊1 ，孙 毅1 嵇 ( 1． 西安建筑科技大学材料科学与工程学院，西安 710055; 2． 西部建筑科技国家重点实验室，西安 710055) 摘要: 新型干法水泥窑系统存在硫循环动态平衡，即部分硫始终处于系统当中参与动态循环，硫循环与系统结皮堵 塞和 SO2 排放关系密切。本文通过工业现场 测 试，对比研究高固气比预热分解系统和普通预热分解系统的硫循 环，探讨了硫收支动态平衡和硫动态循环机理，提出用硫循环度 ε 作为系统中硫参与循环程度的参数，用硫循环动 态平衡理论对高固气比系统 SO2 减排优势进行了解释。研究结果表明通过对硫循环进行操控可以实现对结皮堵 塞防止和 SO2 减排。 关键词: 水泥窑; 硫循环度; SO2 减排 中图分类号: TQ172 文献标识码: A 文章编号: 1001-1625( 2011) 05-1023-06 Study on Sulfur Cycle of Dynamic Equilibrium in NSP Cement Kiln System JI Ying1，2 ，YANG Kang1 ，XU De-long1，2 ，ZHOU Rui1 ，SUN Yi1 ( 1． School of Materials Science and Engineering，Xi＇an University of Architecture and Technology，Xi＇an 710055，China; 2． State Key Laboratory of Architecture Science and Technology in West China，Xi＇an 710055，China) Abstract: Sulfur derived from fuels or raw meals will accumulate and circulate within NSP cement kiln systems; a sulfur circulation within system can result in choking of preheaters，and increased SO2 emission in the exit gases． In this paper，comparisons of the sulfur circulation between the high solid gas ratio preheating and precalcining system and the conventional preheating and precalcining system with data as measured in operating cement manufacturing plants． Discusses the dynamic balance of sulfur payments and mechanism of sulfur dynamic circulation． Proposed with sulfur cycle ε degrees as system in the degree of sulfur cycle parameters． Advantage in reducing SO2 emission with an application of high solid gas ratio preheating and precalcining system was also discussed． It is concluded that an effective control in sulfur circulations would alleviate choking or coating in kiln system，and lead to reduction in SO2 emission． Key words: cement kiln; sulfur circulation ratio; SO2 emissions 1 引 言 在硅酸盐水泥生产中，预热器-分解炉-窑系统( 以下简称系统) 的硫主要由原料及燃料引入。燃料在窑 头和分解炉燃烧生成的 SO2 ，均被此处碱性氧化物和 CaO 吸收成硫酸盐，同时在窑头和分解炉形成硫动态富 基金项目: 陕西省科技工业攻关资助项目( 2010K07-02) ; 陕西省重点学科建设专项资金资助项目 作者简介: 嵇 鹰( 1966-) ，男，副教授． 主要从事新型干法水泥预