高铌tial合金与陶瓷型壳的界面反应.pdf

RareMetalMaterialsandEngineering Availableonlineatwww．sciencedirect．com Volume42，Issue8，August2013 OnlineEnglisheditionoftheChineselanguagejourna 摊摊 bScciieenncceeDiirreecctt Citethisarticleas：RareMetalMaterialsandEngineering，2013，42(8)：1568—1571 Interface Reaction between CeramicMouldsand High Nb-TiAIAlloys LinXiude， XueXiangyi， ZhongHong， ZhangTiebang， LiJinshan StateKeyLaboratoryofSolidificationProcessing,Northwestern PolytechnicalUniversity,Xian710072,China Abstract：TheinterfacereactionbetweenTi一44Al一8Nb一0．2W一0．1B一0．1Y (at％)alloyandA1203／ZrO2Y／203crucibleswasinvesti— gated．Thethicknessesofhteinterfacereactionlayersareabout40，170and20gm．Themostinterestingisthemicrosturcturetrans— formationofTi一44A1—8Nb一0．2W一0．1B一0．1Y solidifyingindifferentcrucibles．AftersolidifyinginAI203／ZrO2／Y203curcibles．the oxygencontentsinTi一44A1—8Nb一0．2W一0．1B一0．1YalloyarcmeasuredtobeO．35，O．41and0．11(at％)．Duringmeltingandsolidifica— tion，oxygenincrucibleswilldiffuseintothealloymatrix．Highoxygencontentcausesmicrosturcturetransformation．Peritecticre— actionoccursinthealloyssolidifyinginA1203andZrO2curcibles．Forcontrast，Ti-49．5AI一2Cr一2Nballoywaschosentomakein— vestigation．Novisiblemicrostructuredifferenceisfoundinalloyssolidifiedinvariouscruciblesthoughtheoxygencontentsarede— terminedas0．40，0．63and0．25(at％)． Keywords：highNb—TiAIalloys；interfacereaction；oxygen；microstructuretransfomr ation In recentyears，highNb containingTiA1alloyshaveat— as．castingotsin Ti．Al—O tem a~ system andenhancesthe ， tractedmoreandmoreattentionfortheirbetteroxidationre— volumerfaction intheTiA1alloys．Therefore．itsextremely sistanceandtensilestrengthatelevatedtemperaturecompraed necessarytopickoutapropercruciblewhichcanreducethe withconventionalTiA1alloysl【_3】