紫外光强化钛柱撑型蒙脱土除砷吸附剂的研制.PDFVIP

2007 年 5 月 　　 　化 　学 　工 　业 　与 　工 　程 第 24 卷 　第 3 期 　 May 2007 CHEMICAL 　INDUSTRY　AND 　EN GINEERIN G Vol . 24 　　No . 3 ( ) 　　文章编号 :1004 - 9533 2007 03 - 0199 - 04 紫外光强化钛柱撑型蒙脱土除砷吸附剂的研制 张海燕 ,张 　帆 ,马新宾 ,毕慧超 ,韩 　　 ,那 　平 (天津大学化工学院 ,天津 300072) 摘要 :制备了对水体中的砷具有良好吸附效果的柱撑蒙脱土 。研究了在紫外光照射的强化作用下 的除砷效果 ,并确定了适宜的吸附砷工艺条件 。结果表明经过压力溶弹处理的钛柱撑蒙脱土 , Ti 元素有效地替换了蒙脱土层间的Al 元素 ,形成锐钛矿型 TiO 柱撑结构 , 晶型发育比较完全 ,可以 2 有效地去除水体中的砷 。 关键词 :砷 ;钛柱撑蒙脱土 ;紫外光照射 ;吸附 中图分类号 :TQ42424 　文献标识码 :A Preparation of TiPillared Montmorillonite to Remove Arsenic Under UV Irradiation ZHAN G Haiyan , ZHAN G Fan , MA Xinbin , BI Huichao , HAN Xi , NA Ping ( School of Chemical Engineering and Technology , Tianj in University , Tianj in 300072 , China) Abstract :An adsorbent Tipillared montmorillonite ( TiPILC) with high efficiency to remove arsenic in water was prepared . The effect on removing arsenic under ultraviolet light irradiation has been analyzed and suitable conditions of preparation have been found . The results indicate that TiPILC which was disposed at certain temperature and pressure for hours can better remove arsenic in water than the others , and the aluminum in the ( ) interval of Namontmorillonite NaMMT has been replaced by titanium effectively , during which anataseTiO